163524-41-2

Upstream product

• 18143-30-1 2-trimethylsilylethanethiol 
• 624-31-7 4-tolyl iodide 
• 106-45-6 para-thiocresol 
• 754-05-2 ethenyltrimethylsilane 

Downstream Products

• 1858-86-2 Ethyl p-toluenesulfinate 
• 10381-70-1 benzyl 4-methylphenyl sulfoxide 
• 934-72-5 Methyl p-tolyl sulfoxide 
• 6378-07-0 ethyl (p-tolyl)sulfoxide 
• 17336-78-6 2-(trimethylsilyl)ethyl chloride 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 153123-09-2 (R_S)-p-Tolyl β-(trimethylsilyl)ethyl sulfoxide 
• 143505-42-4 1-[(4-methylphenyl)sulfinyl]-2-(trimethylsilyl)ethane 

Relevant academic research and scientific papers

3-bisalkylated-2-indolone derivative and preparation method thereof

The invention provides a 3-bisalkylated-2-3-bisalkylated-2-indolone derivative. The derivative has a structural formula represented by a formula I shown in the description, wherein R1 and R2 are halogen or H. The invention further provides a preparation m

Nondirected Copper-Catalyzed Sulfoxidations of Benzylic C-H Bonds

A copper-catalyzed sulfoxidation of benzylic C-H bonds by nondirected oxidative C(sp3)-H activation was developed. The process proceeds via sulfenate anions, which are generated by base-triggered elimination of β-sulfinyl esters and benzyl radicals. The functional group tolerance is high, and the product yields are good.

Stereoretentive palladium-catalyzed arylation, alkenylation, and alkynylation of 1-thiosugars and thiols using aminobiphenyl palladacycle precatalyst at room temperature

A general and efficient protocol for the palladium-catalyzed functionalization of mono- and polyglycosyl thiols by using the palladacycle precatalyst G3-XantPhos was developed. The C-S bond-forming reaction was achieved rapidly at room temperature with various functionalized (hetero)aryl-, alkenyl-, and alkynyl halides. The functional group tolerance on the electrophilic partner is typically high and anomer selectivities of thioglycosides are high in all cases studied. New sulfur nucleophiles such as thiophenols, alkythiols, and thioaminoacids (cysteine) were also successfully coupled to lead to the most general and practical method yet reported for the functionalization of thiols.

2-(trimethylsilyl)ethyl sulfoxides as a convenient source of sulfenate anions

The present report describes the novel and smooth generation of sulfenate salts by fluoride-mediated cleavage of 2-(trimethylsilyl)ethyl sulfoxides. Efficiency of the process was elucidated through further reaction with alkyl halides to give stable sulfox

Asymmetric chemical oxidations of aryl and alkyl 2-(trimethylsilyl)ethyl sulfides

A collection of aryl and alkyl 2-(trimethylsilyl)methyl sulfides have been converted to their respective sulfoxides by four different asymmetric oxidizing agents. The chemical yields range from 44-98% while the enantiomeric excesses range from 0-89%. The

The reaction of 2-trimethylsilylethyl sulfoxides with sulfuryl chloride. A fragmentation route to sulfinyl chlorides

Sulfinyl chlorides were prepared in good to excellent yields by reacting aryl or alkyl 2-trimethylsilylethyl sulfoxides with SO2Cl2.