153153-30-1

Upstream product

• 108-24-7 acetic anhydride 
• 136883-91-5 (2R,3S,4R)-3,4-bis(benzyloxy)-2-((benzyloxy)methyl)-3,4-dihydro-2H-pyran-5-carbaldehyde 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 2873-29-2 D-glucal triacetate 
• 100-39-0 benzyl bromide 
• 153547-53-6 1,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-hydroxymethyl-D-arabino-hex-1-enitol 

Downstream Products

• 153082-00-9 methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-(methylene)-α-D-arabinohexopyranoside 
• 115096-28-1 3,4,6-tri-O-benzyl-2-deoxy-2-methylene-D-arabino-hexono-1,5-lactone 
• 850220-29-0 1-O-acetyl-3,4,6-tri-O-benzyl-4-O-formyl-D-arabino-hex-2-ulose 
• 850220-31-4 1,2-di-O-acetyl-3,4,6-tri-O-benzyl-D-fructofuranose 
• 14233-64-8 tri-O-benzyl-D-arabinolactone 
• 1146980-45-1 (2R,3S,12aR)-2,3,5,12a-tetrahydro-2-benzyloxymethyl-3-benzyloxypyrano[2,3-b]naphtho[1,2-e]pyran 
• 1350934-14-3 1,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-C-(p-methoxyphenylthiomethyl)-D-arabino-hex-1-enitol 
• 1350934-12-1 1,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-C-(phenylthiomethyl)-D-arabino-hex-1-enitol 
• 1350934-13-2 1,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-C-(p-methylphenylthiomethyl)-D-arabino-hex-1-enitol 

Relevant academic research and scientific papers

Diversity-Oriented Synthetic Endeavors of Newly Designed Ferrier and Ferrier-Nicholas Systems Derived from 1-C-Alkynyl-2-deoxy-2-C-Methylene Pyranosides

Novel pyranose derivatives that display Ferrier- and Ferrier-Nicholas-like reactivity have been designed. These systems: 1-C-alkynyl-2-deoxy-2-C-methylene pyranosides (Ferrier), and their corresponding dicobalthexacarbonyl alkenyl derivatives (Ferrier-Nic

Stereoselective synthesis of a ketohexofuranose from an aldohexopyranose by a [6+1-1] strategy

Ozonolysis of 2-acetoxymethyl-1,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-D- arabino-hex-1-enitol gave 1-O-acetyl-3,4,6-tri-O-benzyl-4-O-formyl-D-arabino- hex-2-ulose (5). Subsequent hydrolysis and acetylation of 5 provided 1,2-di-O-acetyl-3,4,6-tri-O-benzyl-D

A New Ferrier System: 2-C-Acetoxymethylglycals. A Convenient Entry to 2-C-Methylene Glycosides

Synthesis of tri-O-benzyl-2-C-acetoxymethylglycals and subsequent Ferrier rearrangement to give 2-C-methylene glycosides is described.