153358-06-6

Basic information

• Product Name: Methanamine, N-[[2-(diphenylphosphino)phenyl]methylene]-
• CAS NO: 153358-06-6
• Molecular Formula: C20H18NP
• Molecular Weight: 303.343
• Mol File: 153358-06-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methanamine, N-[[2-(diphenylphosphino)phenyl]methylene]-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanamine, N-[[2-(diphenylphosphino)phenyl]methylene]-(153358-06-6)
• EPA Substance Registry System: Methanamine, N-[[2-(diphenylphosphino)phenyl]methylene]-(153358-06-6)

Safety Data

• Hazardous Substances Data: 153358-06-6(Hazardous Substances Data)

Upstream product

• 50777-76-9 (2-formylphenyl)(diphenyl)phosphine 
• 74-89-5 methylamine 

Downstream Products

• 343881-00-5 [palladium(II)-bis(pentafluorophenyl)(o-(Ph₂P)C₆H₄-CH=NMe)] 
• 223264-58-2 (CH₃NC(H)C₆H₄P(C₆H₅)2)Pd(C(CH₃)2CHCH₂)⁽¹⁺⁾*BF₄^(1-)=(CH₃NC(H)C₆H₄P(C₆H₅)2)Pd(C(CH₃)2CHCH₂)BF₄ 
• 306972-50-9 [W(CO)4((C₆H₅)2PC₆H₄CHNCH₃)] 
• 343881-07-2 [palladium(II)-(pentafluorophenyl)Cl(o-(Ph₂P)C₆H₄-CH=NMe)] 
• 306972-41-8 [Mo(CO)4((C₆H₅)2PC₆H₄CHNCH₃)] 
• 420845-47-2 Pd(C₄(COOCH₃)4)(P(C₆H₅)2C₆H₄CHNCH₃) 
• 654666-92-9 [Ni((i-PrOCS₂)(o-Ph₂PC₆H₄CH=NMe)]ClO₄ 
• 217813-25-7 Pd(phenyl)I(N-[2-(diphenylphosphanyl)benzylidene]-N-methylamine) 
• 253789-16-1 [Pd(azobenzene)(Ph₂P(o-C₆H₄-CH=N-Me))](PF₆) 
• 253789-30-9 [Pd(phenylpyridinate)(Ph₂P(o-C₆H₄-CH=N-Me))](PF₆) 
• 654666-84-9 [Ni((EtOCS₂)(o-Ph₂PC₆H₄CH=NMe)]ClO₄ 
• 654666-68-9 [Ni((i-Pr₂NCS₂)(o-Ph₂PC₆H₄CH=NMe)]ClO₄ 
• 153358-14-6 N-Methyl-N-propionyl-2-(diphenylphosphino) benzylamine 
• 127171-70-4 N-(2-(diphenylphosphino)benzyl)-N-methylamine 

Relevant articles and documents

POLYMERIZABLE DERIVATIVES OF TRIPHENYLPHOSPHINE. ACYLATION OF TRIARYLPHOSPHINES BEARING ALCOHOL OR AMINE SUBSTITUENTS WITH ACRYLOYLCHLORIDE AND METHACRYLOYLCHLORIDE

Methods to prepare amino substituted triaryl-phosphines viz.N-methyl-2-(diphenylphosphino)benzylamine, N-t-butyl-2-(diphenylphosphino)benzylamine and α,N-dimethyl-4-(diphenylphosphino)benzylamine are presented.The acylation of amino and alcohol substituted triarylphosphines have been studied and the amides N-methacryloyl-N-methyl-4-(diphenylphosphino)benzylamine, N-methacryloyl-2-(diphenylphosphino)aniline, N-methacryloyl-N-methyl-4-(diphenylphosphino)benzylamine, N-methyl-N-propionyl-4-(diphenylphosphino)benzylamine, N-methyl-N-propionyl-2-(diphenylphosphino)benzylamine and N-acryloyl-N-methyl-4-(diphenylphosphino)benzylamine and the ester 2-(diphenylphosphino)benzyl methacrylate have been prepared. Key words: Phosphine; monomer; acylation; acryloylchloride; methacryloylchloride polymer-bound.