15340-78-0

Basic information

• Product Name: Acetic acid 13-methylpodocarpa-8,11,13-trien-12-yl ester
• Synonyms: Acetic acid 13-methylpodocarpa-8,11,13-trien-12-yl ester
• CAS NO: 15340-78-0
• Molecular Formula: C20H28O2
• Molecular Weight: 300.44
• Mol File: 15340-78-0.mol
• Article Data: 3

Chemical Properties

• Melting Point: 102-103 °C
• Boiling Point: 383.8±31.0 °C(Predicted)
• Appearance: /
• Density: 1.017±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Acetic acid 13-methylpodocarpa-8,11,13-trien-12-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid 13-methylpodocarpa-8,11,13-trien-12-yl ester(15340-78-0)
• EPA Substance Registry System: Acetic acid 13-methylpodocarpa-8,11,13-trien-12-yl ester(15340-78-0)

Safety Data

• Hazardous Substances Data: 15340-78-0(Hazardous Substances Data)

Upstream product

• 206554-13-4 Formic acid (4bS,8aS)-2,4b,8,8-tetramethyl-4b,5,6,7,8,8a,9,10-octahydro-phenanthren-3-yl ester 
• 206554-12-3 (4bS,8aS)-2,4b,8,8-Tetramethyl-4b,5,6,7,8,8a,9,10-octahydro-phenanthrene-3-carbaldehyde 
• 206554-11-2 ((4bS,8aS)-2,4b,8,8-Tetramethyl-4b,5,6,7,8,8a,9,10-octahydro-phenanthren-3-yl)-methanol 
• 165619-89-6 (4bS,8aS)-2,4b,8,8-Tetramethyl-4b,5,6,7,8,8a,9,10-octahydro-phenanthrene-3-carboxylic acid methyl ester 
• 58795-27-0 (4aS,8aS)-1,1,4a-Trimethyl-5,6-dimethylene-decahydro-naphthalene 
• 57706-44-2 (+)-(5S,10S)-13-methylpodocarpa-8,11,13-triene 
• 14506-65-1 15,16-dinor-labd-8-en-13-one 
• 515-03-7 sclareol 
• 16736-51-9 8-hydroxy-15,16-dinor-labdan-13-one 
• 949466-06-2 12-acetyl-15,16-dinorpimara-8,11,13-triene 
• 72444-79-2 15,16-dinorpimara-8,11,13-trien-12-ol 
• 108-24-7 acetic anhydride 

Downstream Products

• 561-95-5 nimbiol 

Relevant articles and documents

Highly efficient synthesis of (+)-nimbiol and other podocarpanes derivatives from sclareol

A new access to tricyclic diterpenes of podocarpane skeleton has been opened, in excellent overall yields, and an efficient synthesis of (+)-nimbiol from sclareol has been achieved. Georg Thieme Verlag Stuttgart.

Facile access to optically active ring C aromatic diterpene derivatives from manool. Highly efficient syntheses of (+)-12-methyl-7-oxo-podocarpa-8,11,13-triene-13-carboxylic acid, (+)-13-methyl-7-oxopodocarpa-8,11,13-triene-12-carboxylic acid and (+)-nimbiol

The extension of our recently developed strategy using the key intermediate 2, obtainable in two steps (52% overall yield) from manool 1, to the synthesis of naturally occurring ring C aromatic diterpene derivatives provides in three steps (+)-12-methyl-7-oxopodocarpa-8,11,13-triene-13-carboxylic acid 4b and its isomer 6b, and in seven steps (+)-nimbiol 11b, in good overall yields. This synthesis discloses that the structure 4b assigned to margolone isolated from Azadirachta indica A. Juss is incorrect and needs to be reinvestigated.