16736-51-9Relevant articles and documents
An improved synthesis of rhinocerotinoic acid
Gray, Christopher A.,Davies-Coleman, Michael T.,Rivett, Douglas E. A.
, p. 165 - 173 (2003)
The stereoselective synthesis of E-rhinocerotinoic acid has been achieved in five steps from (-)-sclareol in an overall yield of 32%. This constitutes a significant improvement on the previous synthesis of this anti-inflammatory compound.
Degradation of the side chain of (-)-sclareol: A very short synthesis of nor-ambreinolide and ambrox
Barrero,Alvarez-Manzaneda,Chahboun,Arteaga
, p. 3631 - 3643 (2007/10/03)
The synthesis of nor-Ambreinolide (8) from (-)-sclareol (1) was carried out by treatment with KMnO4-Ac2O and further alkaline hydrolysis. 8 was directly transformed into (-)-ambrox (11) by reduction with metal borohydride in the presence of Lewis acids.
Ozonolytic reactions of the available labdane diterpenoids
Vlad, P. F.
, p. 467 - 468 (2007/10/02)
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