1534433-51-6Relevant articles and documents
Direct arylation of C(sp3)-H bonds in aliphatic amides with diaryliodonium salts in the presence of a nickel catalyst
Iyanaga, Miki,Aihara, Yoshinori,Chatani, Naoto
, p. 11933 - 11939 (2015/02/19)
The Ni(II)-catalyzed direct arylation of C(sp3)-H (methyl and methylene) bonds in aliphatic amides containing an 8-aminoquinoline moiety as the directing group with diaryliodonium salts as coupling electrophiles is described. A wide variety of functional groups are tolerated in the reaction. The reaction represents the first example of the Ni-catalyzed direct arylation of C(sp3)-H bonds with diaryliodonium salts. (Chemical Equation Presented).