153698-15-8

Basic information

• Product Name: [Pd(dba)(dppp)]
• CAS NO: 153698-15-8
• Molecular Weight: 753.169
• Mol File: 153698-15-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [Pd(dba)(dppp)](CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(dba)(dppp)](153698-15-8)
• EPA Substance Registry System: [Pd(dba)(dppp)](153698-15-8)

Safety Data

• Hazardous Substances Data: 153698-15-8(Hazardous Substances Data)

Upstream product

• 7379-67-1 d₅-iodobenzene 
• 6737-42-4 1,3-bis-(diphenylphosphino)propane 
• 32005-36-0 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 
• 352-34-1 4-fluoro-1-iodobenzene 
• 13329-40-3 4-Iodoacetophenone 
• 455-13-0 4-Iodobenzotrifluoride 
• 636-98-6 p-nitrobenzene iodide 
• 591-50-4 iodobenzene 
• 624-31-7 4-tolyl iodide 
• 540-37-4 p-aminoiodobenzene 
• 696-62-8 para-iodoanisole 
• 25309-64-2 4-ethyl-1-iodobenzene 
• 17356-09-1 4-iodocumene 
• 625-95-6 3-Iodotoluene 

Relevant articles and documents

Aryl-phenyl scrambling in intermediate organopalladium complexes: A gas-phase study of the mizoroki-heck reaction

The intramolecular aryl-phenyl scrambling reaction within palladium-DPPP-aryl complex (DPPP=1,3-bis(diphenylphosphino)propane) ions was analyzed by state-of-the-art tandem MS, including gas-phase ion/molecule reactions. The Mizoroki-Heck cross-coupling reaction was performed in the gas phase, and the intrinsic reactivity of important intermediates could be examined. Moreover, linear free-energy correlations were applied, and a mechanism for the scrambling reaction proceeding via phosphonium cations was assumed.