15378-40-2

Basic information

• Product Name: trans-1-cyclohexyl-2-buten-1-one
• Synonyms: trans-1-cyclohexyl-2-buten-1-one
• CAS NO: 15378-40-2
• Molecular Weight: 152.236
• Mol File: 15378-40-2.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: trans-1-cyclohexyl-2-buten-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: trans-1-cyclohexyl-2-buten-1-one(15378-40-2)
• EPA Substance Registry System: trans-1-cyclohexyl-2-buten-1-one(15378-40-2)

Safety Data

• Hazardous Substances Data: 15378-40-2(Hazardous Substances Data)

Upstream product

• 106-95-6 allyl bromide 
• 2719-27-9 cyclohexanylcarbonyl chloride 
• 63511-92-2 (E)-crotonaldehyde diethyl acetal 
• 1088-01-3 tricyclohexylborane 
• 64-17-5 ethanol 
• 931-48-6 2-cyclohexylacetylene 
• 18736-82-8 1-cyclohexyl-but-2-en-1-ol 
• 69036-26-6 1-cyclohexyl-3-buten-1-ol 
• 95123-13-0 1-cyclohexylbut-3-en-1-one 
• 2043-61-0 cyclohexanecarbaldehyde 
• 542-18-7 cyclohexyl chloride 
• 4630-82-4 methyl cyclohexylcarboxylate 
• 244176-58-7 5-bromomethyl-3-cyclohexylisoxazoline 
• 79646-42-7 (E)-1-cyclohexyl-2-buten-1-ol 

Downstream Products

• 1415351-65-3 (E,S)-S-4-cyclohexylbut-3-en-2-yl 1H-imidazole-1-carbothioate 
• 1613417-22-3 (S)-(E)-S-4-cyclohexyl-2-(3-methoxyphenyl)but-3-en-2-yl methylcarbamothioate 
• 79646-42-7 (2E,1R)-1-cyclohexyl-2-buten-1-ol 
• 18736-82-8 (2E,1S)-1-cyclohexyl-2-buten-1-ol 
• 1613417-12-1 (S)-(E)-S-4-cyclohexylbut-3-en-2-yl 1H-indol-6-yl(methyl)carbamothioate 
• 1613417-10-9 (S)-(E)-tert-butyl 6-((((4-cyclohexylbut-3-en-2-yl)thio)carbonyl)(methyl)amino)-1H-indole-1-carboxylate 
• 1613417-08-5 (S)-(E)-S-4-cyclohexylbut-3-en-2-yl methyl(pyridin-2-yl)carbamothioate 
• 1613417-05-2 (S)-(E)-S-4-cyclohexylbut-3-en-2-yl 2-methoxyphenyl(methyl)carbamothioate 
• 1415351-95-9 (S)-(E)-S-4-cyclohexylbut-3-en-2-yl 3-methoxyphenyl(methyl)carbamothioate 
• 1613417-03-0 (S)-(E)-S-4-cyclohexylbut-3-en-2-yl 4-chlorophenyl(methyl)carbamothioate 
• 1613417-02-9 (S)-(E)-S-4-cyclohexylbut-3-en-2-yl 4-fluorophenyl(methyl)carbamothioate 
• 1613417-00-7 (S)-(E)-S-4-cyclohexylbut-3-en-2-yl methyl(p-tolyl)carbamothioate 
• 1613416-97-9 (R)-(E)-tert-butyl 6-(4-cyclohexyl-2-mercaptobut-3-en-2-yl)-1H-indole-1-carboxylate 
• 1613416-91-3 (S)-(E)-4-cyclohexyl-2-(3-methoxyphenyl)but-3-ene-2-thiol 

Relevant articles and documents

A new palladium-catalysed synthesis of 1,1-dialkylbuta-1,3-dienes via organoboron intermediates

Iodobenzene and tetrakis(triphenylphosphine)palladium(0) [(C6H5)3P]4Pd catalyse a new synthesis of 1,1-dialkylbuta-1,3-dienes, starting from 1,1-diethoxybut-2-ene and trialkylboranes, in the presence of Schlosser's superbase LIC-KOR.

Cooperative Electrocatalytic and Chemoselective Alcohol Oxidation by Shvo's Catalyst

A new electrocatalytic conversion of alcohols to ketones and aldehydes was developed based on an electrochemical study of Shvo's complex. The oxidation of secondary alcohols was efficiently performed under mild conditions using a catalytic amount of Shvo's catalyst, in combination with a sub-stoichiometric amount of 2,6-dimethoxy-1,4-benzoquinone in N,N-dimethylformamide at 80 °C. The hydroquinone thus formed is continuously reoxidized with the aid of an electrochemical device. Excellent yields for different ketones, aromatic as well as aliphatic and α,β-unsaturated ketones, are obtained. In addition, chemoselectivity towards oxidation of the secondary alcohol is achieved when converting vicinal diols such as 1,2-octanediol and 1,2-decanediol. (Figure presented.).

Iron-catalyzed aerobic oxidation of allylic alcohols: The issue of C=C bond isomerization

An aerobic oxidation of allylic alcohols using Fe(NO3) 3·9H2O/TEMPO/NaCl as catalysts under atmospheric pressure of oxygen at room temperature was developed. This eco-friendly and mild protocol provides a convenient pathway to the synthesis of stereodefined α,β-unsaturated enals or enones with the retention of the C-C double-bond configuration.