1088-01-3Relevant articles and documents
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Brown,Rao
, p. 6428,6431,6434,6435 (1959)
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Barriola, Antonio M.,Valcarcel, Luis A.
, p. 449 - 454 (1990)
Pd-catalyzed three-component reaction of 3-(Pinacolatoboryl)ally acetates, aldehydes, and organoboranes: A new entry to stereoselective synthesis of (Z)- anti -homoallylic alcohols
Horino, Yoshikazu,Aimono, Ataru,Abe, Hitoshi
supporting information, p. 2824 - 2827 (2015/06/16)
The Pd-catalyzed three-component reaction of 3-(pinacolatoboryl)allyl acetates, aldehydes, and organoboranes is described. The reaction is initiated by the formation of an allylic gem-palladium/boryl intermediate, which then undergoes allylation of aldehydes by allylboronates followed by a coupling reaction of in situ generated (Z)-vinylpalladium acetates with organoboranes to provide the (Z)-anti-homoallylic alcohols with high levels of diastereoselectivity and alkene stereocontrol.
Generation of organolithium compounds bearing super silyl ester and their application to Matteson rearrangement
Oda, Susumu,Yamamoto, Hisashi
supporting information, p. 8165 - 8168 (2013/08/23)
It's super-silyl-fragilithyl-ester-aryl-docious: The super silyl group is a strong protecting group for carboxylic acids and provides a method for direct lithiation that is compatible with the ester moiety. Organolithium compounds bearing a super silyl ester react with a variety of electrophiles in high yields (see scheme). The reaction of lithiated super silyl chloroacetate with a boron compound gives α-functionalization of the ester moiety by Matteson rearrangement. Copyright