153896-07-2Relevant academic research and scientific papers
A New and Efficient Preparation of Cyclic Carbodiimides from Bis(iminophosphoranes) and the System Boc2O/DMAP
Molina, Pedro,Alajarin, Mateo,Sanchez-Andrada, Pilar,Elguero, Jose,Jimeno, Maria Luisa
, p. 7306 - 7315 (2007/10/02)
A one-pot synthesis of cyclic carbodiimides which involves reaction of C,C-bis(aryliminophosphoranes) connected by aliphatic bridges with Boc2O in the presence of DMAP is described.The method is also applicable when a heteroatom such as oxygen or nitrogen is incorporated into the tether connecting the two aromatic rings.A conformation study has been carried out on carbodiimide 23a, which possess a central nine-membered ring, using 1H NMR spectroscopy and semiempirical as well as molecular mechanics calculations.
Medium- and large-membered rings from bis(iminophosphoranes): An efficient preparation of cyclic carbodiimides
Molina, Pedro,Alajarin, Mateo,Sanchez-Andrada, Pilar
, p. 5155 - 5158 (2007/10/02)
The new cyclic carbodiimides 3 are synthetized from bis(iminophosphoranes) 2 and Boc2O in the presence of DMAP; similar results can be achieved from the N-Boc-protected bis (iminophosphoranes) and carbon dioxide.
