15397-14-5

Upstream product

• 3315-16-0 silver cyanate 
• 98-88-4 benzoyl chloride 
• 5336-08-3 D-Ribono-1,4-lactone 

Downstream Products

• 89434-94-6 2',3',5'-tri-O-benzoyl[1'-2H]uridine 
• 145369-07-9 Benzoic acid (2S,4S)-4-((1S,2R,5R)-1-hydroxy-5-isopropenyl-2-methyl-cyclohexyl)-5-oxo-tetrahydro-furan-2-ylmethyl ester 
• 145369-06-8 Benzoic acid (2S,4S)-4-((1S,2S,5R)-1-hydroxy-2-isopropyl-5-methyl-cyclohexyl)-5-oxo-tetrahydro-furan-2-ylmethyl ester 
• 145369-04-6 3-deoxy-2,5-di-O-benzoylthreo-γ-lactone 
• 96086-02-1 (5S)-5-(benzoyloxymethyl)-5H-furan-2-one 

Relevant academic research and scientific papers

Stereoselective bromination of β-ribofuranosyl amide. Enantioselective synthesis of (+)-hydantocidin

The synthesis of hydantocidin, a potent herbicidal natural product, is highlighted by a stereoselective bromination of β-D-ribofuranosyl amide to give only the α-bromo β-amide and subsequent spirocyclization about the anomeric position with silver cyanate to form the hydantoin moiety.

Branched-Chain Carbohydrate Lactones from a Samarium(II) Iodide-Promoted Serial Deoxygenation-Carbonyl Addition Reaction

A new deoxygenation-carbonyl addition reaction mediated by samarium(II) iodide (SmI2) in THF/HMPA was examined with carbohydrate lactones and several substrates containing an α-alkoxy carboxylic ester.In a single reaction, these compounds were deoxygenate

BRANCHED CHAIN CARBOHYDRATE LACTONES FROM A TANDEM SmI2 DEHYDROGENATION-CARBONYL ADDITION REACTION

Treatment of a carbohydrate lactone with a ketone in the presence of SmI2-HMPA produces a deoxygenation/carbonyl addition reaction to afford new C2-branched chain carbohydrates.