145369-06-8Relevant academic research and scientific papers
Branched-Chain Carbohydrate Lactones from a Samarium(II) Iodide-Promoted Serial Deoxygenation-Carbonyl Addition Reaction
Enholm, Eric J.,Jiang, Shujun,Abboud, Khalil
, p. 4061 - 4069 (2007/10/02)
A new deoxygenation-carbonyl addition reaction mediated by samarium(II) iodide (SmI2) in THF/HMPA was examined with carbohydrate lactones and several substrates containing an α-alkoxy carboxylic ester.In a single reaction, these compounds were deoxygenate
HIGHLY STEREOSELECTIVE COUPLINGS OF CARBOHYDRATE LACTONES WITH TERPENE KETONES PROMOTED BY SmI2
Enholm, Eric J.,Jiang, Shujun
, p. 6069 - 6072 (2007/10/02)
Lactone 3-deoxycarbohydrates were reacted with samarium diiodide (SmI2) in THF/HMPA and the terpene ketones, (-)-menthone or (+)-dihydrocarvone; a serial reductive deoxygenation and an attendant carbonyl addition reaction afforded C2 branched sugars with
