153992-10-0Relevant articles and documents
Efficient and chemoselective acetalization and thioacetalization of carbonyls and subsequent deprotection using InF3 as a reusable catalyst
Madabhushi, Sridhar,Mallu, Kishore Kumar Reddy,Chinthala, Narsaiah,Beeram, China Ramanaiah,Vangipuram, Venkata Sairam
scheme or table, p. 697 - 701 (2012/02/15)
An efficient and chemoselective method for preparation of acetals and dithioacetals of aldehydes and their deprotection under catalysis of InF 3 is described.
An electroinitiated cation chain reaction: Intramolecular carbon-carbon bond formation between thioacetal and olefin groups
Matsumoto, Kouichi,Fujie, Shunsuke,Ueoka, Koji,Suga, Seiji,Yoshida, Jun-Ichi
, p. 2506 - 2508 (2008/12/23)
(Figure Presented) The treatment of an olefinic thioacetal with a catalytic amount of ArS(ArSSAr)-+B(C6F5) 4-, or the electrolysis of a mixture of an olefinic thioacetal and ArSSAr, gives rise to effective intramolecular carbon-carbon bond formation (see scheme). This transformation opens up great potential for electroinitiated cation chain reactions in organic synthesis.