154195-37-6

Basic information

• Product Name: Butanoic acid, 4-(phenylamino)-, ethyl ester
• CAS NO: 154195-37-6
• Molecular Formula: C12H17NO2
• Molecular Weight: 207.272
• Mol File: 154195-37-6.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Butanoic acid, 4-(phenylamino)-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Butanoic acid, 4-(phenylamino)-, ethyl ester(154195-37-6)
• EPA Substance Registry System: Butanoic acid, 4-(phenylamino)-, ethyl ester(154195-37-6)

Safety Data

• Hazardous Substances Data: 154195-37-6(Hazardous Substances Data)

Upstream product

• 2969-81-5 Ethyl 4-bromobutyrate 
• 62-53-3 aniline 
• 108-86-1 bromobenzene 
• 3422-01-3 tert-butyl phenylcarbamate 
• 100-61-8 N-methylaniline 
• 140-88-5 ethyl acrylate 
• 103-01-5 N-Phenylglycine 
• 361145-43-9 N-benzyloxycarbonyl-γ-aminobutyric acid ethyl ester 
• 4641-57-0 1-phenylpyrrolidin-2-one 
• 64-17-5 ethanol 

Downstream Products

• 4641-57-0 1-phenylpyrrolidin-2-one 
• 1127-74-8 1,2,3,4-tetrahydro-5H-benzo[b] azepin-5-one 
• 154195-32-1 5-bromo-3-chloro-1-phenyl-azepan-2,4-dione 
• 154195-28-5 3-chloro-1-phenyl-azepan-2,4-dione 
• 195314-88-6 {2-[3-phenyl-3-(3-diethylaminocarbonylpropyl)ureido]-4-methoxy-6-tert-butylphenoxy}methoxymethane 
• 220640-20-0 4-[3-(3-tert-butyl-5-methoxy-2-methoxymethoxy-phenyl)-1-phenyl-ureido]-butyric acid 
• 429659-00-7 4-[(4-methylamino-3-nitro-benzoyl)-phenyl-amino]-butyric acid ethyl ester 
• 220640-19-7 3-(3-tert-butyl-5-methoxy-2-methoxymethoxyphenyl)-1-(3-ethoxycarbonylpropyl)-1-phenylurea 
• 154195-25-2 ethyl-4-(N-phenyl-N-chloroacetyl amino) butanoate 

Relevant articles and documents

Visible-Light Photoredox-Catalyzed Giese Reaction: Decarboxylative Addition of Amino Acid Derived α-Amino Radicals to Electron-Deficient Olefins

A tin- and halide-free, visible-light photoredox-catalyzed Giese reaction was developed. Primary and secondary α-amino radicals were generated readily from amino acids in the presence of catalytic amounts of an iridium photocatalyst. The reactivity of the α-amino radicals has been evaluated for the functionalization of a variety of activated olefins.

Alkylation of the α-amino C-H bonds of anilines photocatalyzed by a DMEDA-Cu-benzophenone complex: reaction scope and mechanistic studies

The Cu(ii) complex1incorporating a BP chromophore is a highly active and chemoselective photocatalyst for the alkylation of α-amino C-H bonds of anilines. The reaction was shown to proceed with a broad substrate scope in the absence of additives. Extensive mechanistic studies were performed, in particular using transient absorption spectroscopy, and spectroscopic signatures of key intermediates were identified in the conditions of catalysis. Finally, the ability of1to act as a multitask catalyst was showcased by conducting multi-component CuAAC and olefin hydroalkylation reactions in one-pot.

Synthetic method for conivaptan hydrochloride key intermediate

The invention discloses a synthetic method for a conivaptan hydrochloride key intermediate. The synthetic method comprises the following steps: triggering N-alkylation reaction of aniline and 4-ethylhalobutyrate in an acid-binding agent, taking methyl chl