154319-59-2Relevant academic research and scientific papers
[HP(HNCH2CH2)3N]NO3: An efficient homogeneous and solid-supported promoter for aza and thia-Michael reactions and for Strecker reactions
Fetterly, Brandon M.,Jana, Nirmal K.,Verkade, John G.
, p. 440 - 456 (2006)
In the presence of a catalytic amount of an azaphosphatrane nitrate salt, amines and thiols react readily with Michael acceptors. The salt is also an efficient promoter for the one pot synthesis of α-amino and α-amidonitriles. By anchoring the salt to Merrifield Resin, a reusable heterogeneous catalyst is obtained for these reactions. Evidence is presented for catalysis being attributable solely to the NO3- ion.
Open-Chain Reissert Compounds: One-Pot Synthesis and Utility in Synthesis of Unsymmetrical Imides, α-Acylamino Carboxamides, Imidazolinones, and Hydantoins
Leblanc, Jean-Pierre,Gibson, Harry W.
, p. 1072 - 1077 (2007/10/02)
Acyclic Reissert compounds 2 and bis(Reissert compound)s 3-5 can be conveniently prepared in a biphasic system without isolation of the intermediate α-amino nitriles.Treatment of 2 with sodium hydride affords substituted unsymmetrical imides as 8.Oxidativ
