15436-25-6

Basic information

• Product Name: S-Methyl-S-<2-nitro-phenyl>-N-p-toluolsulfonyl-sulfilimin
• CAS NO: 15436-25-6
• Molecular Weight: 338.408
• Mol File: 15436-25-6.mol

Chemical Properties

• CAS DataBase Reference: S-Methyl-S-<2-nitro-phenyl>-N-p-toluolsulfonyl-sulfilimin(CAS DataBase Reference)
• NIST Chemistry Reference: S-Methyl-S-<2-nitro-phenyl>-N-p-toluolsulfonyl-sulfilimin(15436-25-6)
• EPA Substance Registry System: S-Methyl-S-<2-nitro-phenyl>-N-p-toluolsulfonyl-sulfilimin(15436-25-6)

Safety Data

• Hazardous Substances Data: 15436-25-6(Hazardous Substances Data)

Upstream product

• 3058-47-7 methyl 2-nitrophenyl sulfide 
• 55962-05-5 4-methyl-N-[(E)-phenyl-λ³-iodanylidene]benzenesulfonamide 

Relevant articles and documents

Mn(salen)-catalyzed sulfimidation: What are the real active species in sulfimidation?

An unusual temperature effect on enantioselectivity was found in a study of Mn(salen)-catalyzed sulfimidation. The phenomenon was considered to be attributable to the following reasons: the reaction of Mn(salen) and a nitrenoid precursor (ArI=NTs) provides primarily an Mn-ArINTs adduct which undergoes sulfimidation and transformation to an Mn-nitrenoid species competitively; however, the rates of sulfimidation by the Mn-ArINTs adduct and the Mn-nitrenoid species and of the transformation are dependent on the structure of the catalyst, the nature of ArI=NTs and the presence or absence of a donor ligand.