154492-66-7

Upstream product

• 16358-71-7 2-bromo-1,5-di-tert-butyl-3-methyl-benzene 
• 67-56-1 methanol 
• 154492-64-5 2-bromo-1-(bromomethyl)-3,5-di-tert-butylbenzene 

Downstream Products

• 154492-67-8 2,4-di-t-butyl-6-(methoxymethyl)phenylphosphonous dichloride 
• 323202-41-1 [2,4-di-tert-butyl-6-(methoxymethyl)phenyl](methyl)[2,4-di-tert-butylphenyl-6-oxymethyl]germanium(II) 
• 240121-68-0 2,4-di-tert-butyl-6-methoxymethyl-phenyl-phosphane 

Relevant academic research and scientific papers

Utilization of 2,4-Di-t-butyl-6-(methoxymethyl)phenyl as a New Sterically Protecting Group

A sterically hindered bromobenzene, 2-bromo-1,5-di-t-butyl-3-(methoxymethyl)benzene, was prepared and converted to the corresponding phosphonous dichloride.The dichloride was then utilized to stabilize a low-coordinate phosphorus compound such as 1-2,4-di-t-butyl-6-(methoxymethyl)phenyl-2-(2,4,6-tri-t-butylphenyl)diphosphene.Furthermore, the dichloride gave a cyclization product 1-chloro-2,1-oxophosphaindan with elimination of chloromethane on standing at room temperature.