15453-22-2Relevant academic research and scientific papers
Catalytic Synthesis of Vinyl Carbamates from Carbon Dioxide and Alkynes with Ruthenium Complexes
Mahe, Roger,Sasaki, Yoshiyuki,Bruneau, Christian,Dixneuf, Pierre H.
, p. 1518 - 1523 (2007/10/02)
Terminal alkynes react with carbon dioxide and secondary amines in the presence of ruthenium complexes to afford vinyl carbamates in one step.The reaction has been performed with phenylacetylene, hexyne, and acetylene and with dialkylamines, morpholine, p
Ruthenium-catalyzed synthesis of vinyl carbamates from carbon dioxide, acetylene, and secondary amines
Sasaki, Yoshiyuki,Dixneuf, Pierre H.
, p. 314 - 315 (2007/10/02)
RuCl3·3H2O catalyzed the reaction of CO2, acetylene, and secondary amines giving vinyl carbamates R2NCO2CH=CH2 with a small amount of 2-butadienyl carbamates CH2=C(R2NCO2)CH=CH2.
