154533-85-4

Upstream product

• 154533-77-4 N-(Tetrahydro-pyran-2-yloxy)-benzimidic acid allyl ester 
• 154533-96-7 C₁₂H₁₄ClNO₂ 
• 110-87-2 3,4-dihydro-2H-pyran 
• 698-16-8 benzohydroximoyl chloride 
• 932-90-1 Benzaldoxime 

Downstream Products

• 154491-53-9 N-allyl-N-hydroxybenzamide 
• 51029-26-6 (3,6-dihydro-2H-1,2-oxazin-2-yl)(phenyl)methanone 
• 139302-97-9 2-Benzoyl-3,6-dihydro-6-methoxy-2H-1,2-oxazine 
• 91536-57-1 N-allyl-N-allyloxy-benzamide 
• 639512-99-5 N-allyl-N-(1-methoxy-allyloxy)-benzamide 

Relevant academic research and scientific papers

Synthesis of unsaturated [1,2]oxazines by using sigmatropic rearrangements and the ring-closing metathesis reaction

Various substituted unsaturated [1,2]oxazines have been synthesized by using a [2,3]- or a [3,3]-sigmatropic rearrangement and a ring-closing metathesis reaction as key steps.

Synthesis of N-allylhydroxamic Acids via -Sigmatropic Rearrangement

N-allylhydroxamic acids 3 can be prepared by a novel thermal -rearrangement of appropriate precursor O-tetrahydropyranylhydroximates 2.Such compounds are available from the protected hydroximoyl chlorides via alkoxide displacement.The rearrangement can proceed with modest chirality transfer.