154491-53-9

Upstream product

• 698-16-8 benzohydroximoyl chloride 
• 98-88-4 benzoyl chloride 
• 932-90-1 Benzaldoxime 
• 154533-77-4 N-(Tetrahydro-pyran-2-yloxy)-benzimidic acid allyl ester 
• 154533-96-7 C₁₂H₁₄ClNO₂ 
• 154533-85-4 N-Allyl-N-(tetrahydro-pyran-2-yloxy)-benzamide 
• 52716-05-9 N-allylhydroxylamine 

Downstream Products

• 639512-99-5 N-allyl-N-(1-methoxy-allyloxy)-benzamide 
• 139302-97-9 2-Benzoyl-3,6-dihydro-6-methoxy-2H-1,2-oxazine 
• 51029-26-6 (3,6-dihydro-2H-1,2-oxazin-2-yl)(phenyl)methanone 
• 91536-57-1 N-allyl-N-allyloxy-benzamide 

Relevant academic research and scientific papers

Mechanism of the reaction of lawesson's reagent with N-alkylhydroxamic acids

The mechanism of the reaction under discussion has been established by investigating the products of the reaction between 2,4-bis(4-methoxyphenyl)-1,3, 2,4-dithiadiphosphetane 2,4-disulfide (Lawesson's reagent, LR) and N-alkylhydroxamic acids HAs 1. The p

Synthesis of unsaturated [1,2]oxazines by using sigmatropic rearrangements and the ring-closing metathesis reaction

Various substituted unsaturated [1,2]oxazines have been synthesized by using a [2,3]- or a [3,3]-sigmatropic rearrangement and a ring-closing metathesis reaction as key steps.

Synthesis of N-allylhydroxamic Acids via -Sigmatropic Rearrangement

N-allylhydroxamic acids 3 can be prepared by a novel thermal -rearrangement of appropriate precursor O-tetrahydropyranylhydroximates 2.Such compounds are available from the protected hydroximoyl chlorides via alkoxide displacement.The rearrangement can proceed with modest chirality transfer.

SYNTHESIS of NOVEL N-(PRIMARY)ALKYLHYDROXAMIC ACIDS

Synthesis of N-primary alkylhydroxamic acids is described in this paper by benzoyloxylation (benzoyl peroxide) of n-alkylamine and modification of the usual reaction conditions to stabilise the N-alkyl-O-benzoylhydroxylamine as the hydrochloride; this cir