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Upstream product

• 10034-09-0 1-methoxy-1,3-butadiene 
• 495-18-1 Benzohydroxamic acid 
• 98-88-4 benzoyl chloride 
• 154533-85-4 N-Allyl-N-(tetrahydro-pyran-2-yloxy)-benzamide 
• 154533-77-4 N-(Tetrahydro-pyran-2-yloxy)-benzimidic acid allyl ester 
• 154533-96-7 C₁₂H₁₄ClNO₂ 
• 154491-53-9 N-allyl-N-hydroxybenzamide 
• 639512-99-5 N-allyl-N-(1-methoxy-allyloxy)-benzamide 

Relevant academic research and scientific papers

Synthesis of unsaturated [1,2]oxazines by using sigmatropic rearrangements and the ring-closing metathesis reaction

Various substituted unsaturated [1,2]oxazines have been synthesized by using a [2,3]- or a [3,3]-sigmatropic rearrangement and a ring-closing metathesis reaction as key steps.

From 1-(Silyloxy)butadiene to 4-Amino-4-deoxy-DL-erythrose and to 1-Amino-1-deoxy-DL-erythriol Derivatives via hetero-Diels-Alder Reactions with Acylnitroso Dienophiles

Acylnitroso dienophiles 4 reacted instantly with 1-(silyloxy)butadiene 5α and led in good yield to the regioisomeric cycloadducts 6 (major) and 7 (minor; Scheme 2, Table 1). cis-Hydroxylation of these primary cycloadducts with OsO4 (catalyst) occurred stereospecifically and in high yield (-> 8 and 9, resp.: Scheme 2).It was followed by reductive ring cleavage to give either 1-amino-1-deoxy-DL-erythriol or 4-amino-4-deoxy-DL-erythrose derivatives 10 and 14, respectively, depending on the nature of the reducing agent (Schemes 3 and 4).