15458-61-4

Basic information

• Product Name: 9-oxabicyclo[3.3.1]nonane-2,6-diol
• Synonyms: 9-oxabicyclo[3.3.1]nonane-2,6-diol;2,6-Dihydroxy-9-oxabicyclo[3.3.1]nonane;Einecs 239-478-2
• CAS NO: 15458-61-4
• Molecular Formula: C8H14O3
• Molecular Weight: 158.19496
• EINECS: 239-478-2
• Mol File: 15458-61-4.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 325.3°Cat760mmHg
• Flash Point: 150.6°C
• Appearance: /
• Density: 1.258g/cm³
• Vapor Pressure: 1.79E-05mmHg at 25°C
• Refractive Index: 1.544
• CAS DataBase Reference: 9-oxabicyclo[3.3.1]nonane-2,6-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 9-oxabicyclo[3.3.1]nonane-2,6-diol(15458-61-4)
• EPA Substance Registry System: 9-oxabicyclo[3.3.1]nonane-2,6-diol(15458-61-4)

Safety Data

• Hazardous Substances Data: 15458-61-4(Hazardous Substances Data)

Usage

General Description

9-Oxabicyclo[3.3.1]nonane-2,6-diol, also known as 2,6-Dihydroxy-9-oxabicyclo[3.3.1]nonane, is a synthetic compound with the formula C7H12O3. It is a bicyclic compound with a six-membered oxygen-containing ring and two hydroxyl groups. This chemical is commonly used in organic synthesis and as a building block for various pharmaceuticals and biologically active compounds. It is also used for the creation of novel cyclic structures and as a chiral building block in organic chemistry. Additionally, it has potential applications in the development of new materials and polymers due to its unique molecular structure and reactivity. Overall, 9-Oxabicyclo[3.3.1]nonane-2,6-diol has a wide range of potential uses in the field of chemistry and materials science.

InChI:InChI=1/C8H14O3/c9-5-1-3-7-6(10)2-4-8(5)11-7/h5-10H,1-4H2

Upstream product

• 5259-72-3 cyclo-octa-1,5-diene 
• 108-05-4 vinyl acetate 
• 652132-98-4 exo,exo-9-oxa-bicyclo[3.3.1]nonane-2,6-diol 

Relevant articles and documents

Synthesis and Expansion of Bicyclic Enol Ether: A Probable Precursor for the Synthesis of Macrolide (±)-Pyrenophorin

A convenient procedure for the synthesis and expansion of bicyclic rings has been developed for the production of probable precursors of non-racemic pyrenophorin, an antibiotic dilactone. The major highlight for this new synthetic methodology came from the use of a readily available reagent of easy manipulation, 9-oxabicyclo[3.3.1]nonane-2,6-diol, for the preparation of the bicyclic intermediate, which sequentially was subjected to oxidative cleavage with butyl nitrite resulted in an isomeric mixture, a dioximedilactone and diisoxazoledilactone.

Selectivity of Candida rugosa lipase in simultaneous separation of skeletal isomers, desymmetrization, and kinetic racemate cleavage of 9-oxabicyclononanediols

The diols 2 and 3, available in one step from cycloocta-1,5-diene, are selectively acetylated at the (R)-centers using Candida rugosa lipase to give the corresponding enantiopure compounds. In contrast, the (S,S)-enantiomer of 11 is transformed under iden