1546-10-7Relevant articles and documents
SYNTHESIS OF FLUOROAROMATIC COMPOUNDS FROM THE CYCLOPENTADIENE DERIVATIVES BY REACTIONS WITH CHLOROFLUOROCARBENE UNDER PHASE-TRANSFER CATALYSIS
Nefedov, O. M.,Volchkov, N. V.
, p. 86 (1991)
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Mechanistic switch via subtle ligand modulation: Palladium-catalyzed synthesis of α,β-substituted styrenes via C-H bond functionalization
Flores-Gaspar, Areli,Martin, Ruben
, p. 1223 - 1228 (2011/06/26)
A new catalyst system able to efficiently perform the synthesis of styrenes via C-H bond functionalization and a subtle ligand modification are described. The high level of activity achieved allows for the synthesis of highly functionalized α,β-substituted styrenes, even the elusive E-configured trisubstituted olefins, in a regio- and stereoselective manner. Mechanistic experiments allowed for the identification of the corresponding synthetic intermediates.
