154701-64-1Relevant academic research and scientific papers
Chiral Mercaptoaryl-oxazolines as Ligands in Asymmetric Catalysis: Enantioselective Cu-Catalyzed 1,4-Addition of Grignard Reagents to α,β-Unsaturated Ketones
Zhou, Qi-Lin,Pfaltz, Andreas
, p. 7725 - 7728 (1993)
Copper(I) thiolate complexes derived from chiral mercaptophenyl-oxazolines 3 have been studied as enantioselective catalysts for the 1,4-addition of Grignard reagents to α,β-unsaturated ketones.For cyclic enones enantioselectivities increase in the sequen
Chiral Mercaptoaryl-oxazolines as Ligands in Enantioselective Copper-Catalyzed 1,4-Additions of Grignard Reagents to Enones
Zhou, Qi-Lin,Pfaltz, Andreas
, p. 4467 - 4478 (2007/10/02)
A series of chiral enantiomerically pure mercaptoaryl-oxazolines has been synthesized.Copper(I) thiolate complexes derived from these ligands proved to be efficient catalysts for the 1,4-addition of Grignard reagents to cyclic enones.Enantioselectivities
