155016-85-6

Upstream product

• 76404-30-3 Benzyl-2,3,6-tridesoxy-α-L-erythro-hex-2-enopyranosid 
• 62-23-7 4-nitro-benzoic acid 
• 76404-29-0 phenylmethyl 4-O-acetyl-2,3,6-trideoxy-α-L-erythro-hex-2-enopyranoside 
• 34819-86-8 3,4-di-O-acetyl-6-deoxy-L-glucal 
• 100-51-6 benzyl alcohol 
• 865484-73-7 tert-butyl ((2S,6S)-6-methyl-5-oxo-5,6-dihydro-2H-pyran-2-yl) carbonate 
• 4208-64-4 1-(2-furyl)ethanol 
• 1192-62-7 1-(2-furyl)-1-ethanone 
• 1174754-24-5 (1R,2R,4S,6S)-2-(benzyloxy)-4-methyl-3,7-dioxabicyclo[4.1.0]-heptan-5-one 
• 1334606-85-7 (2R,3R,6S)-2-(benzyloxy)-6-methyl-3,6-dihydro-2H-pyran-3-ol 
• 41728-14-7 6-hydroxy-2-methyl-2H-pyran-3(6H)-one 
• 512809-21-1 benzyl 2,3,6-trideoxy-α-L-hex-2-enopyranosid-4-ulose 

Downstream Products

• 76404-33-6 Benzyl-2,3,6-tridesoxy-α-L-threo-hex-2-enopyranosid 
• 88818-93-3 benzyl 2,3,4-tri-O-acetyl-6-deoxy-α-L-talopyranoside 

Relevant academic research and scientific papers

De novo synthesis of deoxy sugar via a Wharton rearrangement

A highly divergent synthesis of α-fuco-, α-6-deoxy-allo-, α-6-deoxy-altro-pyranosides has been achieved. This route utilizes a Wharton rearrangement as part of a new post-glycosylation transformation strategy.

SYNTHESIS OF ISOMERIC BENZYL 6-DEOXY-α-L-TALO- AND α-L-GULOPYRANOSIDES

Synthesis of benzyl 2,3,4-tri-O-acetyl-6-deoxy-α-L-talopyranoside (6) and its α-L-gulo isomer 7 was performed by a five-step sequence starting from L-rhamnal 1.The L-talo isomer was proved to be identical with the component of O-antigenic polysaccharide o