15520-32-8

Basic information

• Product Name: isopropoxide
• Synonyms: isopropoxide
• CAS NO: 15520-32-8
• Molecular Weight: 59.088
• Mol File: 15520-32-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: isopropoxide(CAS DataBase Reference)
• NIST Chemistry Reference: isopropoxide(15520-32-8)
• EPA Substance Registry System: isopropoxide(15520-32-8)

Safety Data

• Hazardous Substances Data: 15520-32-8(Hazardous Substances Data)

Upstream product

• 29075-95-4 acetylide anion 
• 67-63-0 isopropyl alcohol 
• 54128-17-5 trifluoromethanide 
• 62268-73-9 diphenylcarbene 
• 78448-33-6 1-isopropoxy-2-methyl-propane 

Downstream Products

• 29075-95-4 acetylide anion 
• 67-63-0 isopropyl alcohol 
• 6265-94-7 2-benzylbenzothiazole 
• 54128-17-5 trifluoromethanide 
• 153842-61-6 Mo(NC₆H₃(CH(CH₃)2)2)(CHC(CH₃)2C₆H₅)(OCH(CH₃)2)2 
• 190385-07-0 2-(2-isopropoxyethyl)-1,3-benzothiazole 
• 190384-95-3 2-(isopropoxymethyl)-1,3-benzothiazole 
• 91-22-5 quinoline 
• 1531-30-2 (2-quinolyl)-2-propanone 
• 60814-31-5 2-isopropoxyquinoline 
• 67-64-1 acetone 

Relevant articles and documents

Acidity, basicity, and the stability of hydrogen bonds: Complexes of RO- + HCF3

Ion-molecule complexes of RO- (R = Me, Et, i-Pr) and HCF3 have been studied with Fourier transform ion cyclotron resonance spectrometry. The RO- complexation energies with HCF3 were measured relative to RO-·H2O. These complexes, [ROHCF3]-, have complexation energies on the order of -20 kcal/tool and have low deuterium fractionation factors and are, therefore, hydrogen bonded. The structure of the complexes was studied by isotopic equilibrium experiments and ab initio calculations. All of the complexes studied have the structure RO-·HCF3 even when HCF3 is a stronger acid than ROH. The structure of the complexes can be understood through electrostatic arguments rather than the difference in acidity between the ion and neutral.

Generation, Thermodynamics, and Chemistry of the Diphenylcarbene Anion Radical (Ph2C.-)

Dissociative electron attachment with Ph2C=N produced Ph2C.- (m/z 166).The reactions of Ph2C.- with potential proton donors of known gas-phase acidity were used to bracket PA(Ph2C.-) = 380 +/- 2 kcal mol-1 from which ΔHf0(Ph2C.-) = 81.8 +/- 2 kcal mol-1 was calculated.The reactions of Ph2C.- with CH3OH and C2H5OH proceeded with major and minor amounts, respectively, of a H2.+-transfer channel, forming Ph2CH2, RCHO, and an electron.The kinetic nucleophilicity of Ph2C.- in SN2 displacement reactions with CH3X and C2H5X molecules was shown to be medium, which requires a significant intrinsic barrier in these reaction.The reactions of Ph2C.- with various aldehydes, ketones, and esters were fast and established two principal product-forming channels: (1) H+ transfer if the neutral reactant contains activated C-H bonds and (2) carbonyl addition followed by radical β-fragmentation of one of the groups originally attached to the carbonyl carbon.The order for the ease of radical β-fragmentation in the tetrahedral intermediates was RO > alkyl >> H, and CO2CH3 > CH3.Since the reactions of Ph2C.- with the simple esters HCO2CH3 and CH3CO2CH3 were fast, it should now be possible to examine the reactions of carbonyl-containing organic molecules, which are expected to react slower than these esters and obtain their relative reactivities.