15527-45-4Relevant articles and documents
One-Pot Condensation/Hydrosilylation System for IPN Formation
Iwahara, Takahisa,Kotani, Jun,Ando, Kiyoshi,Yonezawa, Kazuya
, p. 425 - 426 (1995)
A one-pot low-molecular model reaction system of condensation (1) and hydrosilylation (2) was proposed and studied for preparation of a silicon-based IPN.To make the both reactions proceed selectively, selection of catalysts and hydrosilanes were of importance.Effects of homogeneity of the system were also considered.
The cobalt(II) complex of a new tridentate Schiff-base ligand as a catalyst for hydrosilylation of olefins
Gorczyński, Adam,Zaranek, MacIej,Witomska, Samanta,Bocian, Aleksandra,Stefankiewicz, Artur R.,Kubicki, MacIej,Patroniak, Violetta,Pawlu?, Piotr
, p. 71 - 74 (2016/02/26)
Condensation of 1-methyl-2-imidazolecarboxaldehyde with 2-(1-methylhydrazinyl)pyridine results in the synthesis of new, tridentate Schiff-base ligand L, which readily reacts with CoCl2 to form a monometallic [CoLCl2] complex that, upon reduction, functions as active hydrosilylation catalyst. The ligand and the [CoLCl2] catalyst have been characterized spectroscopically (MS, NMR, FTIR) and by single crystal X-ray diffraction techniques. The results of preliminary catalytic experimentation show that the cobalt complex can induce hydrosilylation and dehydrogenative silylation of olefins, depending upon the hydrosilane substrate used.
Organosilicon compound and process for producing organosilicon compound
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, (2008/06/13)
An organosilicon compound having a Si--C--C--Si bond, a C=C--Si bond and/or a CH--CH--Si bond is prepared by reacting an olefin or a substituted olefin with a disilane in the presence of a platinum-containing catalyst. The resulting compound can be further treated with an alkyl lithium, an aryl lithium or a Grignard reagent.