155397-14-1

Basic information

• Product Name: 1-Decanol, 1,1-bis(dimethylphenylsilyl)-
• CAS NO: 155397-14-1
• Molecular Formula: C26H42OSi2
• Molecular Weight: 426.79
• Mol File: 155397-14-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Decanol, 1,1-bis(dimethylphenylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Decanol, 1,1-bis(dimethylphenylsilyl)-(155397-14-1)
• EPA Substance Registry System: 1-Decanol, 1,1-bis(dimethylphenylsilyl)-(155397-14-1)

Safety Data

• Hazardous Substances Data: 155397-14-1(Hazardous Substances Data)

Upstream product

• 110-42-9 Methyl decanoate 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 112-13-0 n-decanoyl chloride 

Downstream Products

• 112-31-2 caprinaldehyde 
• 125828-06-0 1-dimethyl(phenyl)silyldecan-1-ol 
• 125828-13-9 decanoyldimethyl(phenyl)silane 

Relevant articles and documents

1,1-Disilyl alcohols as d1 synthons: Harnessing the 1,2-Brook rearrangement

1,1-Disilyl alcohols like 6 give the silyl ethers like 9 on treatment with base and alkyl halides, in a reaction which may be formulated as the alkylation of the Brook-rearranged carbanion 8. The products can be oxidised to give ketones like 10, showing that this Brook-rearranging system supplies a controlled d1 synthon of the acyl anion class. The alcohols can be prepared from the acid chloride 12 and dimethyl(phenyl)silyllithium, but the intermediate anion 21 need not be worked up; it can be used directly in the alkylation step.