1554-48-9

Basic information

• Product Name: 1,2,4,5-tetrafluoro-3,6-bis[(E)-prop-1-en-1-yl]benzene
• Synonyms: 1,2,4,5-tetrafluoro-3,6-bis[(E)-prop-1-en-1-yl]benzene
• CAS NO: 1554-48-9
• Molecular Weight: 230.205
• Mol File: 1554-48-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2,4,5-tetrafluoro-3,6-bis[(E)-prop-1-en-1-yl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,4,5-tetrafluoro-3,6-bis[(E)-prop-1-en-1-yl]benzene(1554-48-9)
• EPA Substance Registry System: 1,2,4,5-tetrafluoro-3,6-bis[(E)-prop-1-en-1-yl]benzene(1554-48-9)

Safety Data

• Hazardous Substances Data: 1554-48-9(Hazardous Substances Data)

Upstream product

• 392-56-3 Hexafluorobenzene 
• 6524-17-0 (Z)-1-propenyllithium 
• 6386-72-7 (E)-propenyl lithium 
• 327-54-8 1,2,4,5-Tetrafluorobenzene 
• 106-95-6 allyl bromide 
• 4683-67-4 (E)-1,2,3,4,5-pentafluoro-6-(prop-1-en-1-yl)benzene 
• 19140-58-0 1,2,3,4,5-pentafluoro-6-(prop-1-en-1-yl)benzene 

Downstream Products

• 652-36-8 2,3,5,6-tetrafluoroterephthalic acid 
• 1650-26-6 1,2,4,5-Tetrafluor-3,6-bis-(1,2-dibrom-propyl)-benzol 

Relevant articles and documents

[Cu(NHC)]-Catalyzed C-H Allylation and Alkenylation of both Electron-Deficient and Electron-Rich (Hetero)arenes with Allyl Halides

New reactivity of a [Cu(NHC)] (NHC=N-heterocyclic carbene) catalyst is disclosed for the efficient C-H allylation of polyfluoroarenes using allyl halides in benzene at room temperature. The same catalyst system also promotes an isomerization-induced alkenylation of initially the generated allyl arenes when the reaction is run in tetrahydrofuran. Significantly, not only electron-deficient but also electron-rich (hetero)arenes undergo this double-bond migration process, thus leading to alkenylated products. The present system features mild reaction conditions, broad scope with respect to the arene substrates and allyl halide reactants, good functional-group tolerance, and high stereoselectivity.