155417-88-2Relevant academic research and scientific papers
Asymmetric aldol reaction of glyoxal catalyzed by diarylprolinol
Hayashi, Yujiro,Kojima, Masahiro
, p. 2883 - 2885 (2013)
All selection should be this- eeasy: The direct asymmetric aldol reaction of commercial aqueous glyoxal is catalyzed by trifluoromethyl-substituted diarylprolinol 1 to afford a β-formyl-β-hydroxy-α-substituted aldehyde in good yield with excellent anti selectivity and excellent enantioselectivity.
Acceptor specificity in the transglycosylation reaction using Endo-M
Tomabechi, Yusuke,Odate, Yuki,Izumi, Ryuko,Haneda, Katsuji,Inazu, Toshiyuki
experimental part, p. 2458 - 2463 (2011/01/04)
To determine the structural specificity of the glycosyl acceptor of the transglycosylation reaction using endo-β-N-acetylglucosaminidase (ENGase) (EC 3.2.1.96) from Mucor hiemalis (Endo-M), several acceptor derivatives were designed and synthesized. The narrow regions of the 1,3-diol structure from the 4- to 6-hydroxy functions of GlcNAc were found to be essential for the transglycosylation reaction using Endo-M. Furthermore, it was determined that Endo-M strictly recognizes a 1,3-diol structure consisting of primary and secondary hydroxyl groups.
A Straightforward Preparation of Both Enantiomerically Pure 2-O-Benzyl-erythro-Butanetetrols
Flasche, Michael,Scharf, Hans-Dieter
, p. 1543 - 1546 (2007/10/02)
A short and efficient synthesis of both enatiomerically pure 2-O-benzyl-erythro-butanetetrols 4 and ent-4 from the readily available D-erthronolactone 1 is presented.The synthesis proceeds in a highly efficient manner and is in both cases substrate controlled.
C-Furanoside Synthesis via Radical Cyclisation of β-Alkoxyacrylates
Lee, Eun,Park, Cheol Min
, p. 293 - 294 (2007/10/02)
Stereoselective synthesis of C-furanosides is accomplished via tributylstannane-mediated radical cyclisation of β-alkoxyacrylates.
