104322-67-0 Usage
Uses
Used in Pharmaceutical Industry:
(2S,3S)-2-Benzyloxy-3,4-O-isopropylidene-butanol is used as a starting material for the synthesis of various pharmaceuticals and natural products. Its unique structure and reactivity make it a valuable component in the development of new drugs and therapeutic agents.
Used in Organic Synthesis:
(2S,3S)-2-Benzyloxy-3,4-O-isopropylidene-butanol is used as a reagent for the protection of hydroxyl groups in organic synthesis. This allows chemists to temporarily block the reactivity of hydroxyl groups during the synthesis process, facilitating the formation of desired products and preventing unwanted side reactions.
Used as an Intermediate:
(2S,3S)-2-Benzyloxy-3,4-O-isopropylidene-butanol can also be utilized as an intermediate in the production of other organic compounds. Its versatile structure and functional groups make it a useful building block for the synthesis of a wide range of organic molecules.
Check Digit Verification of cas no
The CAS Registry Mumber 104322-67-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,4,3,2 and 2 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 104322-67:
(8*1)+(7*0)+(6*4)+(5*3)+(4*2)+(3*2)+(2*6)+(1*7)=80
80 % 10 = 0
So 104322-67-0 is a valid CAS Registry Number.
InChI:InChI=1/C14H20O4/c1-14(2)17-10-13(18-14)12(8-15)16-9-11-6-4-3-5-7-11/h3-7,12-13,15H,8-10H2,1-2H3/t12-,13+/m1/s1
104322-67-0Relevant academic research and scientific papers
Asymmetric aldol reaction of glyoxal catalyzed by diarylprolinol
Hayashi, Yujiro,Kojima, Masahiro
, p. 2883 - 2885 (2013/10/21)
All selection should be this- eeasy: The direct asymmetric aldol reaction of commercial aqueous glyoxal is catalyzed by trifluoromethyl-substituted diarylprolinol 1 to afford a β-formyl-β-hydroxy-α-substituted aldehyde in good yield with excellent anti selectivity and excellent enantioselectivity.
Diastereoselective synthesis of all eight L-hexoses from L-ascorbic acid
Ermolenko, Ludmila,Sasaki, N. Andre
, p. 693 - 703 (2007/10/03)
A novel versatile method for the synthesis of all eight diastereomerically pure L-hexoses was developed. L-Ascorbic acid was converted to two diastereomers A. These α-hydroxy esters were transformed into four γ-alkoxy- α,β-unsaturated esters C via the int
C-Furanoside Synthesis via Radical Cyclisation of β-Alkoxyacrylates
Lee, Eun,Park, Cheol Min
, p. 293 - 294 (2007/10/02)
Stereoselective synthesis of C-furanosides is accomplished via tributylstannane-mediated radical cyclisation of β-alkoxyacrylates.
STEREOSELECTIVE ALLYLATION FOR PREPARATION OF L-HEXOSE DERIVATIVES
Williams, D. R.,Klinger, Franz D.
, p. 869 - 872 (2007/10/02)
The reaction of allyltrimethylsilane with α,β-dialkoxyaldehydes is catalyzed by magnesium bromide, and provides for a highly stereoselective allylation which is predicted by α-chelation of the Lewis acid.The observed stereocontrol is opposite to that gene
