15545-32-1Relevant academic research and scientific papers
Ag-Cu copromoted direct C2-H bond thiolation of azoles with Bunte salts as sulfur sources
Du, Xiao,Hu, Yuntao,Wang, Rui,Wei, Yingsu,Xu, Hongyan,Zhang, Ying,Zhao, Huaiqing
supporting information, p. 5899 - 5904 (2021/07/12)
A direct C2-H thiolation of azoles with Bunte salts was achieved under the combined action of copper and silver salts. This protocol could furnish various substituted 2-thioazoles in moderate to good yields. This method has a broad substrate scope and shows good functional group tolerance.
Synthetic approaches towards CGA 293'343: A novel broad-spectrum insecticide
Goebel, Thomas,Gsell, Laurenz,Hueter, Ottmar F.,Maienfisch, Peter,Naef, Rudolf,O'Sullivan, Anthony C.,Pitterna, Thomas,Rapold, Thomas,Seifert, Gottfried,Senn, Marcel,Szczepanski, Henry,Wadsworth, David J.
, p. 355 - 357 (2007/10/03)
Synthetic approaches towards CGA 293'343 (ISO draft common name: thiamethoxam), a novel broad-spectrum insecticide from the class neonicotinoids, are described. 2-Chloro-5-chloromethylthiazole, an important synthetic intermediate, was prepared from five different precursors. Alternatively, CGA 293'343 was prepared via the intermediate 2-benzylmercapto-5-chloromethylthiazole, the synthesis of which is also described.
Addition of trimethylsulfoxoniumylide and methylenetriphenylphosphorane to N2-thioacylamidines
Toure, S. A.,Voglozin, A.,Degny, E.,Danion-Bougot, R.,Danion, D.,et al.
, p. 574 - 579 (2007/10/02)
Trimethylsulfoxonium ylide reacts with 4-dimethylamino-1-thia-3-azabutadienes (N2-thioacylamidines) affording thiazol-2-ines, through a regioselective reaction corresponding to a nucleophilic attack on the amidine group.Thiazoles are obtained b
ADDITION OF ORGANOMETALLICS TO α,β-UNSATURATED THIOCARBONYL COMPOUNDS. IV. FIVE-MEMBERED SULFUR HETEROCYCLES BY 1,4-ADDITION OF THE CARBENOID ICH2MgCl
Guemas, Jean-Pierre,Villieras, Jean
, p. 299 - 306 (2007/10/02)
2,3-Dihydrothiophenes, 2-arylthiophenes, 2-methylthio-3-arylthiophenes and 2-substituted thiazoles are prepared by 1,4-addition of iodomethylmagnesium chloride with β-aminopropenethiones, methyl β-aminopropenedithioate and thioacylformamidines.
