155687-76-6Relevant academic research and scientific papers
Benzyl Methyl (S)-2-(p-Tolylsulfinyl)maleate, an Efficient Dienophile in Asymmetric Diels-Alder Reactions
Alonso, Ines,Carretero, Juan C.,Ruano, Jose L. Garcia
, p. 1499 - 1508 (1994)
The enantiomerically pure dienophile 3 was readily prepared in a three-step sequence from benzyl acetate and (-)-(S)-menthyl p-toluenesulfinate (46percent overall yield).This vinyl sulfoxide reacted in high
Benzyl Methyl (S)-2-(p-Tolylsulfinyl)maleate: An Efficient Dienophile for the Enantioselective Synthesis of Cyclohexadienes
Alonso, Ines,Carretero, Juan C.,Ruano, Jose L. Garcia
, p. 3231 - 3232 (2007/10/02)
The new dienophile, benzyl methyl (S)-2-(p-tolylsulfinyl)maleate, readily prepared in two steps from benzyl acetate, reacts with a wide variety of 1,3-dienes, under catalysis by TiCl4, in a very regioselective and stereoselective manner to give optically
