Benzyl Methyl (S)-2-(p-Tolylsulfinyl)maleate, an Efficient Dienophile in Asymmetric Diels-Alder Reactions

DOI: 10.1021/jo00085a043

Source and publish data:

Journal of Organic Chemistry p. 1499 - 1508 (1994)

Update date:2022-08-03

Topics:

Authors:

Alonso, Ines

Carretero, Juan C.

Ruano, Jose L. Garcia

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00085a043

The enantiomerically pure dienophile 3 <1-benzyl 4-methyl (S)-(p-tolylsulfinyl)maleate> was readily prepared in a three-step sequence from benzyl acetate and (-)-(S)-menthyl p-toluenesulfinate (46percent overall yield).This vinyl sulfoxide reacted in high

Full text of DOI:10.1021/jo00085a043

Products guided by the article

Product name:(R₁,S₂,S_S)-1-Benzyl 2-methyl 1-p-(tolylsulfinyl)-4-cyclohexene-1,2-dicarboxylate

Cas No:155687-76-6

R&D Labs maybe for 155687-76-6

Rayfull Holding Co., Ltd

Contact:+86-577-65618087-605

Address:Room 402, Unit 4 Xinhu Bldg. Waitan Ruian City, Zhejiang China.
Hubei Lingsheng Pharmaceuticals Co., Ltd.

Contact:+86-0710-3538058

Address:Xiangyang City Xiangcheng Economic Development Zone, Hubei Province
BAODING SINO-CHEM INDUSTRY CO.,LTD

Contact:0312-5956088

Address:NO.8 FUXING ROAD,CHINA
Taizhou Sunny Chemical Co.,Ltd

Contact:+86-523-86920899 +86-13951172783

Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China
QINGDAO HONG JIN CHEMICAL CO.,LTD.

website:http://www.hongjinchem.com

Contact:+86-532-83657313

Address:2ND Building, 8 Shangqing Road, Qingdao, Shandong Province, China.

Relevant to this article

Skeletal reorganization of enynes catalyzed by a Ru(2)Ru(3) mixed-valence complex under an atmosphere of O² or CO

Doi:10.1246/cl.130785
(2013)
Synthesis of some novel aromatic alkynyl silanes: Mesomorphic characterization of ethynyl-substituted rod-shaped molecules

Doi:10.1080/15421406.2013.822299
(2014)
Design, synthesis, and optimization of balanced dual NK₁/NK ₃ receptor antagonists

Doi:10.1021/ml400528y
(2014)
Synthesis of 8-halogenated-7-deaza-2′-deoxyguanosine as an 8-oxo-2′-deoxyguanosine analogue and evaluation of its base pairing properties

Doi:10.1016/j.tet.2014.01.047
(2014)
Nitridotris(neopentyl)molybdenum(VI)

Doi:10.1021/ja00090a055
(1994)
Stereoselective synthesis of optically active 4-ethyl-3,5-dihydroxy-2- methylpentyl derivatives. A basic building block with three contiguous chiral centers of polyether antibiotics

Doi:10.1248/cpb.41.2044
(1993)

Article Doi