Benzyl Methyl (S)-2-(p-Tolylsulfinyl)maleate, an Efficient Dienophile in Asymmetric Diels-Alder Reactions

DOI: 10.1021/jo00085a043

Source and publish data:

Journal of Organic Chemistry p. 1499 - 1508 (1994)

Update date:2022-08-03

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Authors:

Alonso, Ines

Carretero, Juan C.

Ruano, Jose L. Garcia

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Article abstract of DOI:10.1021/jo00085a043

The enantiomerically pure dienophile 3 <1-benzyl 4-methyl (S)-(p-tolylsulfinyl)maleate> was readily prepared in a three-step sequence from benzyl acetate and (-)-(S)-menthyl p-toluenesulfinate (46percent overall yield).This vinyl sulfoxide reacted in high

Full text of DOI:10.1021/jo00085a043

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