155701-32-9Relevant academic research and scientific papers
Intramolecular homolytic displacements. 25. Efficient access to epoxides via induced decomposition of unsaturated peroxyketals prepared by addition of a hydroperoxide to 2-methoxypropene
Ramon, Fabienne,Degueil-Castaing, Marie,Maillard, Bernard
, p. 2071 - 2074 (1996)
The synthetic potential of homolytically induced decompositions of peroxyketals possessing a 1-methoxy-1-methylethoxy fragment, as a means of access to epoxides, was demonstrated. The propagation step of this free radical reaction proceeds via (i) the add
Stereoselectivity of the intramolecular homolytic substitution in the induced decomposition of methacrylic-type peroxidic compounds
Colombani, Daniel,Maillard, Bernard
, p. 14855 - 14864 (2007/10/03)
Tile stereochemistry of the oxiranes, obtained by radical induced decomposition of various peroxydic compounds, was determined by NMR spectroscopy. The stereoselectivity of the intramolecular homolytic substitution on the peroxidic bond was discussed in relation to the effect of the reaction temperature and on the influence of structural factors such as the nature of the leaving and attacking radicals.
