15601-98-6

Basic information

• Product Name: (1E,2E)-dipropylidenehydrazine
• Synonyms: 4,5-Diazaocta-3,5-diene
• CAS NO: 15601-98-6
• Molecular Formula: C₆H₁₂N₂
• Molecular Weight: 112.1729
• Mol File: 15601-98-6.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 146.871°C at 760 mmHg
• Flash Point: 33.736°C
• Density: 0.822g/cm³
• Vapor Pressure: 5.747mmHg at 25°C
• Refractive Index: 1.44
• CAS DataBase Reference: (1E,2E)-dipropylidenehydrazine(CAS DataBase Reference)
• NIST Chemistry Reference: (1E,2E)-dipropylidenehydrazine(15601-98-6)
• EPA Substance Registry System: (1E,2E)-dipropylidenehydrazine(15601-98-6)

Safety Data

• Hazardous Substances Data: 15601-98-6(Hazardous Substances Data)

Upstream product

• 123-38-6 propionaldehyde 
• 71-23-8 propan-1-ol 

Downstream Products

• 5039-61-2 n-propylhydrazine 
• 1615-83-4 1,2-di-n-propylhydrazine 
• 107-10-8 propylamine 
• 142-84-7 di-n-propylamine 
• 110-17-8 (2E)-but-2-enedioic acid 
• 821-67-0 azopropane 
• 17697-55-1 di-n-propyldiazene N-oxide 
• 302-01-2 hydrazine 
• 113854-49-2 1-phenyl-3-(4-nitrophenyl)-5-ethyl-1,2,4-triazole 
• 1029-38-5 5-ethyl-1,3-diphenyl-1H-1,2,4-triazole 
• 56930-57-5 2-benzhydryl-4-ethyl-5,5-diphenyl-4,5-dihydro-[1,3]oxazin-6-one 
• 56930-55-3 2-benzhydrylidene-4-ethyl-5,5-diphenyl-3-propylideneamino-[1,3]oxazinan-6-one 

Relevant articles and documents

Unprecedented synthesis of symmetrical azines from alcohols and hydrazine hydrate using nickel based NNN-pincer catalyst: An experimental and computational study

Azines are having widespread applications in both industry as well as synthetic chemistry. Thus new catalytic synthetic protocols are desirable as they are greener alternatives than traditional methods of synthesis. Thus, herein a novel earth abundant nickel based NNN-pincer catalyst Ni(BPEA)(Cl2) is synthesized for the first time for the direct transformation of alcohols and hydrazine hydrate into symmetrical azines. This catalytic reaction is accompanied by dehydrogenative coupling of alcohols and hydrazine hydrate and is carried out in presence of a base. Theoretical calculations supported by experimental evidence have been performed for understanding the mechanistic insights of the reaction.