156726-61-3Relevant articles and documents
Synthesis of 4-amino-3,4-dideoxy-D-arabino-heptulosonic acid 7-phosphate, the biosynthetic precursor of C7N units in ansamycin antibiotics
Kirschning, Andreas,Bergon, Philippe,Wang, Jeh-Jeng,Breazeale, Steven,Floss, Heinz G.
, p. 245 - 256 (1994)
The synthesis of 4-amino-3,4-dideoxy-D-arabino-heptulosonic acid 7-phosphate (15), the first committed intermediate in a new branch of the shikimate pathway of aromatic biosynthesis, is reported from 2-deoxy-D-glucose in 14 steps in 10-12percent overall y