Synthesis of 4-amino-3,4-dideoxy-D-arabino-heptulosonic acid 7-phosphate, the biosynthetic precursor of C7N units in ansamycin antibiotics

DOI: 10.1016/0008-6215(94)84211-6

Source and publish data:

Carbohydrate Research p. 245 - 256 (1994)

Update date:2022-08-04

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Authors:

Kirschning, Andreas

Bergon, Philippe

Wang, Jeh-Jeng

Breazeale, Steven

Floss, Heinz G.

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Article abstract of DOI:10.1016/0008-6215(94)84211-6

The synthesis of 4-amino-3,4-dideoxy-D-arabino-heptulosonic acid 7-phosphate (15), the first committed intermediate in a new branch of the shikimate pathway of aromatic biosynthesis, is reported from 2-deoxy-D-glucose in 14 steps in 10-12percent overall y

Full text of DOI:10.1016/0008-6215(94)84211-6

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