2880-95-7

Basic information

• Product Name: Methyl(methyl3-deoxy-D-arabino-hept-2-ulopyranosid)onate
• Synonyms: Methyl(methyl3-deoxy-D-arabino-hept-2-ulopyranosid)onate
• CAS NO: 2880-95-7
• Molecular Formula: C₉H₁₆O₇
• Molecular Weight: 236.218
• Mol File: 2880-95-7.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 385.4±42.0 °C(Predicted)
• Appearance: /
• Density: 1.39±0.1 g/cm3(Predicted)
• PKA: 13.08±0.70(Predicted)
• CAS DataBase Reference: Methyl(methyl3-deoxy-D-arabino-hept-2-ulopyranosid)onate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl(methyl3-deoxy-D-arabino-hept-2-ulopyranosid)onate(2880-95-7)
• EPA Substance Registry System: Methyl(methyl3-deoxy-D-arabino-hept-2-ulopyranosid)onate(2880-95-7)

Safety Data

• Hazardous Substances Data: 2880-95-7(Hazardous Substances Data)

Upstream product

• 91294-64-3 2-deoxy-3,4:5,6-di-O-isopropylidene-D-arabino-hexose propylene dithioacetal 
• 91294-63-2 2-deoxy-D-arabino-hexose propylene dithioacetal 
• 61-58-5 2-deoxy-D-arabino-hexopyranose 
• 211934-99-5 2,6-anhydro-4,5,7-tri-O-benzyl-1-(propane-1,3-diyl-dithioacetal)-1,3-dideoxy-D-arabino-hept-1-enitol 
• 79999-46-5 (4R,5S,6R)-4,5-bis(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-one 
• 182677-56-1 ethyl (2,4,5,7-tetra-O-acetyl-3-deoxy-D-arabino-2-heptulopyranosid)onate 
• 146303-99-3 ethyl 2,3-dideoxy-2-(hydroxyimino)-4,5:6,7-di-O-isopropylidene-D-arabino-heptonate 
• 67-56-1 methanol 
• 56742-43-9 3-deoxy-2-keto-D-arabino-heptonic acid 
• 119005-61-7 methyl (methyl 4,5,7-tri-O-benzyl-3-deoxy-α-D-arabino-hept-2-ulopyranosid)onate 
• 85464-51-3 (2R,4R,5S,6R)-4,5-Diacetoxy-6-acetoxymethyl-2-methoxy-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 91294-65-4 methyl 3-deoxy-4,5:6,7-di-O-isopropylidene-D-arabino-hept-2-ulosonate 

Downstream Products

• 90318-58-4 diphenyl 7-phosphate 
• 87461-25-4 (2R,3S,4R)-6,7-Bis-(phenyl-hydrazono)-heptane-1,2,3,4-tetraol 
• 118893-84-8 Methyl (methyl 4,5-di-O-acetyl-7-O-trityl-3-deoxy-D-arabino-heptulopyranosid)onate 
• 156726-63-5 methyl (methyl 5,7-O-benzylidene-3-deoxy-D-ribo-heptulopyranosid)onate 
• 156726-67-9 methyl (methyl 4-azido-3,4-dideoxy-D-arabino-heptulopyranosid)onate 7-(diphenylphosphate) 
• 156726-65-7 methyl (methyl 4-azido-5,7-O-benzylidene-3,4-dideoxy-D-arabino-heptulopyranosid)onate 
• 156726-62-4 methyl (methyl 5,7-O-benzylidene-3-deoxy-4-oxo-D-arabino-heptulopyranosid)onate 
• 90318-59-5 methyl (methyl 3-deoxy-α-D-arabino-hept-2-ulopyranosid)onate 7-(dihydrogen phosphate) 
• 194155-51-6 (2R,4S,5R,6R)-4,5-Diacetoxy-6-(tert-butyl-diphenyl-silanyloxymethyl)-2-methoxy-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 194155-49-2 (2R,4R,5S,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-4,5-dihydroxy-2-methoxy-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 194155-55-0 (2R,4S,5R,6R)-4,5-Dihydroxy-6-hydroxymethyl-2-methoxy-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 118893-83-7 Methyl(methyl 7-O-trityl-3-deoxy-D-arabino-heptulopyranosid)onate 
• 156726-61-3 methyl (methyl 5,7-O-benzylidene-3-deoxy-D-arabino-heptulopyranosid)onate 

Relevant articles and documents

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The first synthesis of the ketene dithioacetals from sugar lactones: A convenient access to 3-ulosonic acids

Isomeric 2-deoxy aldonolactones undergo Horner-Emmons reactions with 2- [bis(2,2,2-trifluoroethoxy)phosphoryl]1,3-dithiane, to give the corresponding ketene dithioacetals, which are the key intermediates in the synthesis of 3- deoxy-2-keto-aldonic acids.

Synthesis of 4-amino-3,4-dideoxy-D-arabino-heptulosonic acid 7-phosphate, the biosynthetic precursor of C7N units in ansamycin antibiotics

The synthesis of 4-amino-3,4-dideoxy-D-arabino-heptulosonic acid 7-phosphate (15), the first committed intermediate in a new branch of the shikimate pathway of aromatic biosynthesis, is reported from 2-deoxy-D-glucose in 14 steps in 10-12percent overall y