156753-34-3Relevant academic research and scientific papers
Palladium-catalyzed oxidative C-H bond acylation of acetanilides with benzylic alcohols
Yuan, Yu,Chen, Duanteng,Wang, Xiaowei
supporting information; experimental part, p. 3373 - 3379 (2012/02/03)
An efficient and clean method to construct C-C bonds has been developed via the acylation reaction of acetanilides with benzylic alcohols using tert-butyl hydroperoxide (TBHP) as oxidant catalyzed by palladium acetate in the presence of triflic acid (TfOH). The acylation reactions exhibit excellent reactivities, and up to 95% yield of the corresponding aryl ketone could be obtained under the optimal conditions. Copyright
Pyrolysis of Aryl Azides. XII. Mechanistic Implications of the Very Small Neighbouring Group Effects Across the 2,3-Bond of 2-Azidonaphthalene
Dyall, Leonard K.,Ferguson, John A.
, p. 1031 - 1042 (2007/10/02)
2-Azidonaphthalenes with nitro, acetyl, benzoyl and methoxycarbonyl substituents in the 3-position have been synthesized and then pyrolysed in nitrobenzene solution.At 120 deg C, the rates (relative to 2-azidonaphthalene) are respectively 27.9, 24.8, 5.00
