15677-13-1Relevant articles and documents
Synthesis and Analysis of Substituted Bullvalenes
Yahiaoui, Oussama,Pa?teka, Luká? F.,Judeel, Bernadette,Fallon, Thomas
, p. 2570 - 2574 (2018)
Herein we detail a practical synthesis of bullvalene and a variety of mono- and disubstituted analogues through cobalt-catalysed [6+2] cycloaddition of cyclooctatetraene to alkynes, followed by photochemical di-π-methane rearrangement. The application of isomer-network analysis, coupled with quantum-chemical calculations, provides a powerful automated tool for predicting the properties of bullvalene isomer networks.
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Masamune,S. et al.
, p. 2727 - 2728 (1968)
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van Tamelen,Burkoth
, p. 151 (1967)
N-Phenyltriazolinedione Adducts of Bicyclodecatetraene and Tricyclo2,8>decatriene(Bullvalene)
Joesel, Rainer,Schroeder, Gerhard
, p. 1428 - 1437 (2007/10/02)
Bicyclodecatetraene (1) and bullvalene (8) generate cycloadducts 3 and 9 with N-phenyltriazolinedione (2).Base-induced hydrolysis and subsequent oxidation give tetracyclic and tricyclic azo compounds 6 and 12, respectively. 6 has a half-life of ca.