156808-53-6

Upstream product

• 106-45-6 para-thiocresol 
• 58680-49-2 p-tolyl p-tolylthiomethyl sulfone 
• 52317-51-8 p-Toluyl-p-toluylthiomethylsulfoxid 
• 17241-04-2 bis(p-tolylthio)methane 
• 17609-16-4 p-CH₃C₆H₄SO₂CH₂Li 
• 71425-56-4 (p-Toluolsulfinylmethyl)-p-toluylsulfon 
• 1517-74-4 1-(isopropylsulfinyl)-4-methylbenzene 
• 201664-67-7 C₁₇H₂₀O₃S₂ 

Downstream Products

• 201664-70-2 4-Methyl-N-[1-methyl-2-(toluene-4-sulfonyl)-2-p-tolylsulfanyl-ethyl]-N-((E)-3-phenyl-allyl)-benzenesulfonamide 
• 156808-54-7 p-tolyl 1-p-tolylthioallyl sulfone 

Relevant academic research and scientific papers

Heterocyclic synthesis by C-C bond formation. Thionium ion-mediated preparation of substituted pyrrolidines and piperidines

Dithioacetal-S,S-dioxides 6 and 7 undergo cyclisation to give pyrrolidines and piperidines upon exposure to Lewis acid. An unexpected tandem cyclisation of 5 to give 10 is described.

Radical-induced 1,3-Rearrangemets of Allylic Sulfones bearing an Alkylthio or Arylthio Substituent at the α-Position

1-Methylthio-1-p-tolylsulfonylprop-2-ene 2 underwent 1,3-rearrangement under conditions of radical initiation with migration of the p-tolylsulfonyl group by a process considered to have involved addition-elimination of arylsulfonyl radicals.In contrast, t