156875-61-5Relevant academic research and scientific papers
Synthesis of Diaryl Diselenides Having Chiral Pyrrolidine Rings with C2 Symmetry. Their Application to the Asymmetric Methoxyselenylation of trans-β-Methylstyrenes
Fujita, Ken-ichi,Iwaoka, Michio,Tomoda, Shuji
, p. 923 - 926 (1994)
Optically active diaryl diselenides carrying C2 symmetrical chiral pyrrolidines are synthesized by the condensation between 2,2'-diselenobis(benzyl chloride) derivatives and chiral pyrrolidines and are applied to methoxyselenylation of trans-ol
Design of optically active selenium reagents having a chiral tertiary amino group and their application to asymmetric inter- and intramolecular oxyselenenylations
Fujita, Ken-ichi,Murata, Kazuhisa,Iwaoka, Michio,Tomoda, Shuji
, p. 2029 - 2048 (2007/10/03)
A new class of chiral selenium reagents 4-7 was synthesized on the basis of the concept that the strong intramolecular interaction between an electrophilic selenium and an optically modified tertiary amine (Se··N interaction) would induce asymmetric induc
