1569-59-1

Basic information

• Product Name: 3-METHYL-4-PENTEN-2-OL
• Synonyms: 3-METHYL-4-PENTEN-2-OL
• CAS NO: 1569-59-1
• Molecular Formula: C₆H₁₂O
• Molecular Weight: 100.16
• Mol File: 1569-59-1.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 124.7°C at 760 mmHg
• Flash Point: 41.3°C
• Appearance: /
• Density: 0.828g/cm³
• Vapor Pressure: 5.88mmHg at 25°C
• Refractive Index: 1.426
• CAS DataBase Reference: 3-METHYL-4-PENTEN-2-OL(CAS DataBase Reference)
• NIST Chemistry Reference: 3-METHYL-4-PENTEN-2-OL(1569-59-1)
• EPA Substance Registry System: 3-METHYL-4-PENTEN-2-OL(1569-59-1)

Safety Data

• Hazardous Substances Data: 1569-59-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H12O/c1-4-5(2)6(3)7/h4-7H,1H2,2-3H3

Upstream product

• 60-29-7 diethyl ether 
• 75-07-0 acetaldehyde 
• 13292-87-0 dimethylsulfide borane complex 
• 4866-55-1 cis-2,3-dimethylmethylenecyclopropane 
• 5070-00-8 (-)-trans-2,3-dimethylmethylenecyclopropane 
• 1826-67-1 vinyl magnesium bromide 
• 591-97-9 1-chloro-2-butene 
• 6088-87-5 2-butenylmagnesium bromide 
• 21969-32-4 crotylmagnesium chloride 
• 3200-73-5 trans-2-butenyltrimethylstannane 
• 22032-77-5 (E)-crotylmagnesium chloride 
• 67570-20-1 Dibutyl-(2-butenyl)-borane 
• 917-64-6 methyl magnesium iodide 
• 1838-94-4 isoprene epoxide 

Downstream Products

• 2088-05-3 3,5-dinitro-benzoic acid-(1,2-dimethyl-but-3-enyl ester) 
• 75477-62-2 Toluene-4-sulfonic acid 1,2-dimethyl-but-3-enyl ester 
• 83542-41-0 (E)-3-methyl-5-phenyl-4-pentene-2-one 
• 565-62-8 3-methylpent-3-en-2-one 
• 758-87-2 3-methyl-4-penten-2-one 
• 1567220-06-7 (2S)-ethyl 2-(7-(4-(allyloxy)-4-methylpieridin-1-yl)-5-methyl-2-(5‘-methyl-2‘-((3-methylpent-4-en-2-yl)oxy)-[1,1‘-biphenyl]-3-yl)pyrazolo[1,5-a]pyrimidin-6-yl)-2-(tert-butoxy)acetate 
• 1567220-02-3 4,4,5,5-tetramethyl-2-(5-methyl-2-((3-methylpent-4-en-2-yl)oxy)phenyl)-1,3,2-dioxaborolane 
• 1567219-97-9 2-bromo-4-methyl-1-((3-methylpent-4-en-2-yl)oxy)benzene 

Relevant articles and documents

Alkenes as chelating groups in diastereoselective additions of organometallics to ketones

Alkenes have been discovered to be chelating groups to Zn(II), enforcing highly stereoselective additions of organozincs to β,γ-unsaturated ketones. 1H NMR studies and DFT calculations provide support for this surprising chelation mode. The results expand the range of coordinating groups for chelation-controlled carbonyl additions from heteroatom Lewis bases to simple C-C double bonds, broadening the 60 year old paradigm.

STEREOCHEMICAL AND SPECTROSCOPIC STUDIES ON THE REACTION OF ALLYLSTANNANES WITH ALDEHYDES

The orientational preference for the reacting double bonds in the Lewis acid-induced reaction of allylic stannanes and aldehydes has been examined.Model system 1 shows a strong and Lewis-acid independent preference for the synclinal orientation of double

SUBSTITUTION REACTIONS INVOLVING ORGAOALUMINUM COMPOUNDS. COMMUNICATION 4. SYNTHESIS OF ALKYL-SUBSTITUTED CYCLOPROPANES VIA THE ALKYLATION OF HOMOALLYLIC ALCOHOL TOSYLATES WITH TRIALKYLALANES

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