157117-26-5

Basic information

• Product Name: (1R,4'S,5'S)-1-<4'-(t-butyldiphenylsilyl)oxymethyl-2'-phenyl-4',5'-dihydrooxazol-5'-yl>pentadecan-1-ol
• Synonyms: (1R,4'S,5'S)-1-<4'-(t-butyldiphenylsilyl)oxymethyl-2'-phenyl-4',5'-dihydrooxazol-5'-yl>pentadecan-1-ol
• CAS NO: 157117-26-5
• Molecular Weight: 642.01
• Mol File: 157117-26-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R,4'S,5'S)-1-<4'-(t-butyldiphenylsilyl)oxymethyl-2'-phenyl-4',5'-dihydrooxazol-5'-yl>pentadecan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4'S,5'S)-1-<4'-(t-butyldiphenylsilyl)oxymethyl-2'-phenyl-4',5'-dihydrooxazol-5'-yl>pentadecan-1-ol(157117-26-5)
• EPA Substance Registry System: (1R,4'S,5'S)-1-<4'-(t-butyldiphenylsilyl)oxymethyl-2'-phenyl-4',5'-dihydrooxazol-5'-yl>pentadecan-1-ol(157117-26-5)

Safety Data

• Hazardous Substances Data: 157117-26-5(Hazardous Substances Data)

Upstream product

• 220869-70-5 (1R,2R,4'S,5'S)-1-<4'-(t-butyldiphenylsilyl)oxymethyl-2'-phenyl-4',5'-dihydrooxazol-5'-yl>propane-1,2,3-triol 
• 157117-17-4 2-Benzamido-2-deoxy-4,6-O-ethylidene-D-glucitol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 220869-71-6 (4S,5S)-4-(t-butyldiphenylsilyl)oxymethyl-2-phenyl-4,5-dihydrooxazole-5-carbaldehyde 
• 110220-87-6 n-tetradecylmagnesium chloride 
• 157117-23-2 (4S,5S)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-phenyl-5-((2R,3S)-3-tridecyl-oxiranyl)-4,5-dihydro-oxazole 
• 157117-18-5 Methanesulfonic acid (1R,2S)-2-benzoylamino-3-(tert-butyl-diphenyl-silanyloxy)-1-((2R,4S,5R)-5-methanesulfonyloxy-2-methyl-[1,3]dioxan-4-yl)-propyl ester 
• 157117-22-1 Toluene-4-sulfonic acid (2S,3S)-3-[(4S,5S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-2-phenyl-4,5-dihydro-oxazol-5-yl]-oxiranylmethyl ester 
• 157117-19-6 Methanesulfonic acid (2R,4S,5R)-4-[(4S,5S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-2-phenyl-4,5-dihydro-oxazol-5-yl]-2-methyl-[1,3]dioxan-5-yl ester 
• 157117-20-9 Methanesulfonic acid (1R,2S)-2-[(4S,5S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-2-phenyl-4,5-dihydro-oxazol-5-yl]-2-hydroxy-1-hydroxymethyl-ethyl ester 
• 157117-21-0 {(2S,3S)-3-[(4S,5S)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-phenyl-4,5-dihydro-oxazol-5-yl]-oxiranyl}-methanol 
• 15890-72-9 laurylmagnesium bromide 
• 220869-68-1 2-benzamido-2-deoxy-1-O-t-butyldiphenylsilyl-4,6-O-ethylidene-3-O-methylsulfonyl-D-glucitol 

Downstream Products

• 220869-77-2 (1R,4'S,5'S)-1-<4'-(3'',4'',6''-tri-O-acetyl-2''-chloroacetamido-2''-deoxy-β-D-glucopyranosyl)oxymethyl-2'-phenyl-4',5'-dihydrooxazol-5'-yl>pentadecan-1-ol 
• 157117-30-1 N-[(1S,2S,3R)-1-(tert-Butyl-diphenyl-silanyloxymethyl)-2,3-dihydroxy-heptadecyl]-benzamide 
• 220869-75-0 (1R,4'S,5'S)-1-<4'-hydroxymethyl-2'-phenyl-4',5'-dihydrooxazol-5'-yl>pentadecan-1-ol 
• 554-62-1 D-ribo-phytosphingosine 

Relevant articles and documents

Stereocontrolled synthesis of novel phytosphingosine-type glucosaminocerebrosides

D-ribo-Phytosphingosine 1 was conveniently synthesized from N-benzoyl- D-glucosamine 3 by an improved route in which regioselective O- methanesulfonation and diastereoselective Grignard addition are involved as key steps. Using a synthetic intermediate of 1, novel D-ribo- phytosphingosine-type glycolipids 2a and 2b, unnatural homologues of antifungal cerebrosides Halicylindrosides, were efficiently synthesized in a stereocontrolled manner.