157117-30-1

Basic information

• Product Name: N-[(1S,2S,3R)-1-(tert-Butyl-diphenyl-silanyloxymethyl)-2,3-dihydroxy-heptadecyl]-benzamide
• Synonyms: N-[(1S,2S,3R)-1-(tert-Butyl-diphenyl-silanyloxymethyl)-2,3-dihydroxy-heptadecyl]-benzamide
• CAS NO: 157117-30-1
• Molecular Weight: 660.025
• Mol File: 157117-30-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-[(1S,2S,3R)-1-(tert-Butyl-diphenyl-silanyloxymethyl)-2,3-dihydroxy-heptadecyl]-benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(1S,2S,3R)-1-(tert-Butyl-diphenyl-silanyloxymethyl)-2,3-dihydroxy-heptadecyl]-benzamide(157117-30-1)
• EPA Substance Registry System: N-[(1S,2S,3R)-1-(tert-Butyl-diphenyl-silanyloxymethyl)-2,3-dihydroxy-heptadecyl]-benzamide(157117-30-1)

Safety Data

• Hazardous Substances Data: 157117-30-1(Hazardous Substances Data)

Upstream product

• 157117-18-5 Methanesulfonic acid (1R,2S)-2-benzoylamino-3-(tert-butyl-diphenyl-silanyloxy)-1-((2R,4S,5R)-5-methanesulfonyloxy-2-methyl-[1,3]dioxan-4-yl)-propyl ester 
• 157117-22-1 Toluene-4-sulfonic acid (2S,3S)-3-[(4S,5S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-2-phenyl-4,5-dihydro-oxazol-5-yl]-oxiranylmethyl ester 
• 157117-19-6 Methanesulfonic acid (2R,4S,5R)-4-[(4S,5S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-2-phenyl-4,5-dihydro-oxazol-5-yl]-2-methyl-[1,3]dioxan-5-yl ester 
• 157117-23-2 (4S,5S)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-phenyl-5-((2R,3S)-3-tridecyl-oxiranyl)-4,5-dihydro-oxazole 
• 157117-20-9 Methanesulfonic acid (1R,2S)-2-[(4S,5S)-4-(tert-butyl-diphenyl-silanyloxymethyl)-2-phenyl-4,5-dihydro-oxazol-5-yl]-2-hydroxy-1-hydroxymethyl-ethyl ester 
• 157117-26-5 (1R,4'S,5'S)-1-<4'-(t-butyldiphenylsilyl)oxymethyl-2'-phenyl-4',5'-dihydrooxazol-5'-yl>pentadecan-1-ol 
• 157117-17-4 2-Benzamido-2-deoxy-4,6-O-ethylidene-D-glucitol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 15890-72-9 laurylmagnesium bromide 
• 157117-21-0 {(2S,3S)-3-[(4S,5S)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-phenyl-4,5-dihydro-oxazol-5-yl]-oxiranyl}-methanol 

Downstream Products

• 554-62-1 D-ribo-phytosphingosine 

Relevant articles and documents

Regio- and stereocontrolled synthesis ofD-erythrosphingosine and phytosphingosine fromDglucosamine

D-erythro-Sphingosine (1) and phytosphingosine (2) have been efficiently synthesized from D-glucosamine by utilizing its whole carbon skeleton and functional groups. In this synthetic route, regioselective alkylation of the epoxy-tosylate 9 was achieved with a copper(I)-catalyzed Grignard reagent to give the key intermediate 10, which was converted to both 1 and 2 via regioselective formation of the iodohydrin 11.