15720-16-8Relevant academic research and scientific papers
Assembly of homolinear α(1→2)-linked nonamannoside on ionic liquid support
Ma, Qing,Sun, Sheng,Meng, Xiang-Bao,Li, Qing,Li, Shu-Chun,Li, Zhong-Jun
experimental part, p. 5652 - 5660 (2011/09/30)
An improved method for the synthesis of large and complex oligosaccharides on ionic liquid (IL) support was developed. A strategy to attach the acceptor on IL using a more stable ether linker was used to prevent undesirable decomposition and side products
Ionic liquids as reaction media for esterification of carboxylate sodium salts with alkyl halides
Brinchi,Germani,Savelli
, p. 2027 - 2029 (2007/10/03)
Ionic liquids based on 1,3-dialkylimidazolinium methanesulfonate have been used as effective reusable reaction media in the esterification of several carboxylate sodium salts with different alkyl halides. Products are easily isolated by extraction with ether, and the protocol is mild and green, compared to the existing methods based on toxic solvents. Proper 'design' of the ionic liquid allows us to obtain esters always in quantitative yields.
26. Multiple Adducts of C60 by Tether-Directed Remote Functionalization and Synthesis of Soluble Derivatives of New Carbon Allotropes Cn(60 + 5)
Isaacs, Lyle,Diederich, Francois,Haldimann, Richard F.
, p. 317 - 342 (2007/10/03)
A comprehensive series of multiple adducts of C60 was prepared by tether-directed remote functionalization. When the tether-reactive-group conjugates 2 and 10 were attached to methano[60]fullerenecarboxylic acid = cyclopropafullerene-C60/
Synthesis of 4-phosphono- and of 4-(phosphonomethyl)-dl-phenylalanine, two analogues of O-phosphotyrosine
Bayle-Lacoste, Mireille,Moulines, Jean,Collignon, Noel,Boumekouez, Abdelkader,De Tinguy-Moreaud, Eliane,Neuzil, Eugene
, p. 7793 - 7802 (2007/10/18)
:4-Phosphono-DL-phenylalanine 1 was synthetized from 4-bromo-DL-phenylalanine or from 4-(bromomethyl)-bromobenzene ; 4-(phosphonomethyl)-DL-phenylalanine 14 was prepared from methyl p-toluate. The interest of these phosphonic analogues arises from their possible interference in the metabolism of O-phosphotyrosine.
