1574184-70-5

Basic information

• Product Name: 5-methyl-2-(pyridin-2-yl)phenyl 4-methoxybenzoate
• Synonyms: 5-methyl-2-(pyridin-2-yl)phenyl 4-methoxybenzoate
• CAS NO: 1574184-70-5
• Molecular Weight: 319.36
• Mol File: 1574184-70-5.mol

Chemical Properties

• CAS DataBase Reference: 5-methyl-2-(pyridin-2-yl)phenyl 4-methoxybenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 5-methyl-2-(pyridin-2-yl)phenyl 4-methoxybenzoate(1574184-70-5)
• EPA Substance Registry System: 5-methyl-2-(pyridin-2-yl)phenyl 4-methoxybenzoate(1574184-70-5)

Safety Data

• Hazardous Substances Data: 1574184-70-5(Hazardous Substances Data)

Upstream product

• 637-69-4 4-Methoxystyrene 
• 4467-06-5 2-(4-methylphenyl)pyridine 
• 2393-23-9 4-methoxy-benzylamine 
• 5405-95-8 4,4'-dimethoxydibenzyl ether 

Relevant articles and documents

Benzylic ethers as arylcarboxy surrogates in substrate directed ortho C-H functionalisation catalysed by copper

A copper catalysed ortho-benzoxylation of 2-arylpyridines has been accomplished using benzylic ethers as the alternative arylcarboxy sources (ArCOO-) via sp2 C-H bond activation. The use of the Pd/TBHP catalytic system is reported to install an

Amides and Ethers as Chemoselective Surrogates for Copper(II)-Catalyzed ortho Benzoyloxylation of 2-Phenylpyridines

Chemoselective ortho benzoyloxylation of 2-phenylpyridine derivatives using amides and ethers as novel arylcarboxy sources using a Cu(II)/TBHP catalytic system has been reported. It is a simple protocol for ortho benzoyloxylation using amides and ethers as surrogates. A broad range of amides and ethers was found to be compatible under optimized reaction conditions to provide the corresponding products in good to excellent yield. The reaction proceeds through the cleavage of C-N, C-O, and C-H bonds and the formation of a new C-O bond via C-H functionalization.

Benzylamine as an arylcarboxy surrogate: A copper catalysed o-benzoxylation of 2-phenylpyridines using benzyl amines

Different reactivities and selectivities of Cu and Pd catalysts have been demonstrated in the reactions of benzylamines with 2-phenylpyridines. Although Pd is reported to give o-arylation (ArCO-), Cu introduces an arylcarboxy group (ArCOO-) at the proxima

Terminal aryl alkenes and alkynes as arylcarboxy surrogates toward o -Benzoxylation of 2-phenylpyridine catalyzed by copper

A variety of styrenes and phenylacetylenes serve as excellent arylcarboxy sources in bringing about substrate directed o-benzoxylation of 2-phenylpyridine derivatives catalyzed by Cu(II) in the presence of TBHP. This reaction proceeds via formation of phenylglyoxal followed by decarbonylation to benzoyl radical/benzaldehyde which acts as the arylcarboxy source.