15753-58-9Relevant academic research and scientific papers
Acetylide Ion (C22-) as a synthon to link electrophiles and nucleophiles: A simple method for enaminone synthesis
Yu, Dingyi,Sum, Yin Ngai,Ean, Amanda Chng Cheng,Chin, Mei Ping,Zhang, Yugen
, p. 5125 - 5128 (2013)
Friendly competition: A three-component reaction system composed of calcium carbide, an aryl aldehyde, and an amine gave enaminones or propargylamines (see picture) in a predictable manner through competitive pathways. The system enables the cost-efficient synthesis of a variety of enaminones from readily accessible small molecules and demonstrates the versatility of the acetylide ion, which can be used to bridge electrophiles and nucleophiles. Copyright
