157758-36-6

Upstream product

• 90414-36-1 methyl (3S)-3,4-dihydroxybutyrate 
• 617-55-0 dimethyl (S)-malate 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 124655-05-6 (S)-methyl 4-(tert-butyldiphenylsilyloxy)-3-hydroxybutanoate 

Downstream Products

• 157758-38-8 1-[(2S,3S,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxy)-3-methoxy-2-methyl-hexyloxymethyl]-4-methoxy-benzene 
• 157758-31-1 C₃₁H₅₀O₃Si₂ 
• 157758-37-7 (3S,4S,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxy)-3-methyl-hept-1-en-4-ol 

Relevant academic research and scientific papers

Au-catalyzed cyclization of monopropargylic triols: An expedient synthesis of monounsaturated spiroketals

The gold-catalyzed cyclization of monopropargylic triols to form olefin-containing spiroketals is reported. The reactions are rapid and high yielding when 2 mol % of the catalyst generated in situ from Au[P(t-Bu) 2(o-biphenyl)]CI and AgOTf is e

A Convergent Approach to Swinholide A. Stereoselective Construction of the C3-C17 Fragment of Swinholide A

A strategy for a total synthesis of the cytotoxic dimeric macrolide swinholide A (1, Scheme 1) is outlined and a stereoselective construction of the suitably functionalized C3-C17 fragment 4, starting with building blocks 6, 7, 9 and 10 is described.